Process for the production of dinitrotoluene
View Patent ↗The present invention is directed to a process for the isothermal nitration of aromatic organic compounds, wherein an aromatic organic compound is brought into contact and reacted with a mixture of sulfuric acid and nitric acid. The mixture of sulfuric acid and nitric acid, and the aromatic organic compound are brought into contact with each other through a mixing nozzle which comprises a substantially cylindrical tubular reactor and an annular gap which surrounds the tubular reactor. The aromatic organic compound flows through the tubular reactor, and the mixture of sulfuric acid and nitric acid flows through the annular gap, and they are mixed together upon emerging from the tubular reactor and the annular gap, wherein the ratio of the average rates of flow of the aromatic organic compound in the tubular reactor, and of the mixture of sulphuric acid and nitric acid in the annular gap ranges from 0.5:1 to 10:1.
1. A process for the isothermal nitration of aromatic organic compounds, comprising
(A) contacting (1) an aromatic organic compound, with (2) a mixture of (a) sulfuric acid and (b) nitric acid, via a mixing nozzle which comprises a substantially cylindrical tubular reactor and an annular gap surrounding the cylindrical tubular reactor, in which (1) said aromatic organic compound flows through the tubular reactor, and (2) said mixture of (a) sulfuric acid and (b) nitric acid flows through the annular gap, and (1) and (2) are mixed together upon emerging from the tubular reactor and the annular gap, wherein the ratio of the average rates of flow of (1) aromatic organic compound in the tubular reactor and of (2) the mixture of (a) sulfuric acid and (b) nitric acid in the annular gap ranges from about 0.5:1 to about 10:1; and
(B) reacting the mixture of (1) said aromatic organic compound, and (2) said mixture of (a) sulfuric acid and (b) nitric acid, thereby forming nitrated aromatic organic compounds.
2. The process of claim 1 , wherein (1) said aromatic organic compound is selected from the group consisting of benzene, toluene, phenol, mononitrotoluene and mixtures thereof.
3. The process of claim 1 , wherein (1) said aromatic organic compound, and (2) said mixture of (a) sulfuric acid and (b) nitric acid flow through the mixing nozzle at a speed of 0.3 to 10 m/s.
4. The process of claim 1 , wherein (1) said aromatic organic compound as it passes through the tubular reactor, and/or (2) said mixture of (a) sulfuric acid and (b) nitric acid as it passes through the annular gap, is set in rotation motion by fixed internal fittings.
5. The process of claim 1 , wherein the mixture of (1) said aromatic organic compound, and (2) said mixture of (a) sulfuric acid and (b) nitric acid, emerges from the mixing nozzle with a conical flow profile.