Isoolefin-diolefin production process and apparatus therefore
View Patent ↗In an isoolefin-diolefin rubber production process (e.g. a butyl rubber production process), the cold rubber slurry produced in the reaction vessel is transported from the reaction vessel to the flash tank during which time the cold slurry may be expressed to separate at least part of the cold liquid reaction medium from the isoolefin-diolefin rubber. The separated cold liquid reaction medium is transported off stream, for example by a mechanical filter, where it can be recycled back into the reaction vessel and/or where it can be used to cool a feed stream or streams of the reaction components. The isoolefin-diolefin rubber and the residual liquid reaction medium are transported to a flash tank for further processing. The ability to separate and recycle cold liquid reaction medium makes the process more economical. In one aspect, the slurry may be transported from the reaction vessel to the flash tank by a self-cleaning fully intermeshing co-rotating twin screw extruder, which helps overcome the problem of plugging due to rubber sticking to the surfaces of the slurry transfer apparatus.
1. An apparatus for transferring an isoolefin-diolefin rubber slurry having a temperature in a range of from −110° C. to −50° C. from a reaction vessel to a slurry processing vessel comprising:
(a) a barrel having a first end and a second end;
(b) an inlet proximal the first end for receiving the rubber into the barrel;
(c) an outlet proximal the second end for discharging the rubber from the barrel;
(d) a set of fully intermeshing, co-rotating screws inside the barrel having reverse flights at the second end beyond the outlet;
(e) motor and gearing for rotating the screws; and
(f) a conduit in fluid communication with the barrel at one or more points for transporting the liquid non-aqueous reaction medium separated from a slurry away from the reaction vessel.
2. The apparatus according to claim 1 , wherein the set of screws is a fully intermeshing co-rotating pair of screws.
3. An apparatus for producing an isoolefin-diolefin rubber comprising:
(a) a reaction vessel for preparing a slurry of an isoolefin-diolefin rubber in a liquid non-aqueous reaction medium at a temperature in a range of from −110° C. to −50° C.;
(b) an expression separator in fluid communication with the reaction vessel for separating at least part of the liquid non-aqueous reaction medium in the liquid form from the rubber, the expression separator comprising:
(i) a barrel having a first end and a second end;
(ii) an inlet proximal the first end for receiving the rubber into the barrel from the reaction vessel;
(iii) an outlet proximal the second end for discharging the rubber from the barrel;
(iv) a set of fully intermeshing, co-rotating screws inside the barrel having reverse flights at the second end beyond the outlet;
(v) motor and gearing for rotating the screws;
(c) a slurry processing vessel in fluid communication with the expression separator for receiving residual slurry from the expression separator; and,
(d) a conduit in fluid communication with the expression separator at one or more points between the reaction vessel and the slurry processing vessel for transporting liquid non-aqueous reaction medium separated in liquid form from the rubber by the expression separator out of the expression separator and away from the reaction vessel.