Electrostatic latent image developing magenta toner, electrostatic latent image developer, toner manufacturing method, and image forming method
View Patent ↗An electrostatic latent image developing magenta toner includes at least quinacridone pigment, naphthol pigment, and a release agent. Colorant of the toner satisfies conditions (a) and (b): (a) an average primary particle size D50 of a quinacridone pigment represented by formula (1) and an average primary particle size D50 of a naphthol pigment represented by formula (2) are such that the average primary particle size D50 of the quinacridone pigment is smaller than the average primary particle size D50 of the naphthol pigment; and (b) the average primary particle size D50 of the quinacridone pigment is greater than 20 nm, and the average primary particle size D50 of the naphthol pigment is smaller than 200 nm. Formula (1): Here, each of R 1 , R 2 , R 3 , and R 4 is selected from the group consisting of H, CH 3 , and Cl, R 1 and R 2 are different from each other, and R 3 and R 4 are different from each other. Formula (2):
1. An electrostatic latent image developing magenta toner including a quinacridone pigment, a naphthol pigment, and a release agent, wherein colorant of the toner satisfies conditions (a) and (b) below:
(a) an average primary particle size D50 of a quinacridone pigment represented by formula (1) and an average primary particle size D50 of a naphthol pigment represented by formula (2) are such that the average primary particle size D50 of the quinacridone pigment is smaller than the average primary particle size D50 of the naphthol pigment; and
(b) the average primary particle size D50 of the quinacridone pigment is greater than 20 nm, and the average primary particle size D50 of the naphthol pigment is smaller than 200 nm;
formula (1) being
in which each of R 1 , R 2 , R 3 , and R 4 is selected from the group consisting of H, CH 3 , and Cl; R 1 and R 2 are different from each other; and R 3 and R 4 are different from each other; and
formula (2) being
2. An electrostatic latent image developing magenta toner as defined in claim 1 , wherein the quinacridone pigment includes any one of pigment red 122, pigment red 202, and pigment red 209.
3. An electrostatic latent image developing magenta toner as defined in claim 1 , wherein the naphthol pigment includes any one of pigment red 31, pigment red 146, pigment red 147, pigment red 150, pigment red 176, pigment red 238, and pigment red 269.
4. An electrostatic latent image developing magenta toner as defined in claim 1 , wherein weight ratio of the quinacridone pigment to the naphthol pigment falls within a range of 80:20 to 20:80.
5. An electrostatic latent image developing magenta toner as defined in claim 1 , wherein pigment content within the toner falls within a range of 5 to 15 wt %.
6. An electrostatic latent image developing magenta toner as defined in claim 1 , wherein amount of the release agent added to the toner falls within a range of 5 to 40 wt %.
7. An electrostatic latent image developing magenta toner as defined in claim 1 , wherein shape factor SF1 falls within a range of 115 to 140.
8. An electrostatic latent image developing magenta toner as defined in claim 1 , wherein molecular weight distribution represented by ratio (Mw/Mn) of weight average molecular weight (Mw) to number average molecular weight (Mn) as measured by gel permeation chromatography falls within a range of 2 to 30.
9. An electrostatic latent image developing magenta toner as defined in claim 1 , further including hydrophobicized silica.
10. An electrostatic latent image developing magenta toner as defined in claim 1 , further including silica and a titanium compound.
11. An electrostatic latent image developer comprising an electrostatic latent image developing magenta toner and a carrier;
the magenta toner including a quinacridone pigment, a naphthol pigment, and a release agent, wherein colorant of the toner satisfies conditions (a) and (b) below:
(a) an average primary particle size D50 of a quinacridone pigment represented by formula (1) and an average primary particle size D50 of a naphthol pigment represented by formula (2) are such that the average primary particle size D50 of the quinacridone pigment is smaller than the average primary particle size D50 of the naphthol pigment; and
(b) the average primary particle size D50 of the quinacridone pigment is greater than 20 nm, and the average primary particle size D50 of the naphthol pigment is smaller than 200 nm;
formula (1) being
in which each of R 1 , R 2 , R 3 , and R 4 is selected from the group consisting of H, CH 3 , and Cl; R 1 and R 2 are different from each other; and R 3 and R 4 are different from each other; and
formula (2) being
12. An electrostatic latent image developer as defined in claim 11 , wherein the carrier is coated by a nitrogen-containing resin.
13. An electrostatic latent image developer as defined in claim 11 , wherein the carrier includes a resin obtained by polymerizing acrylic or methacrylic acid alkyl ester having a branched alkyl group.
14. An electrostatic latent image developer as defined in claim 11 , wherein electric resistance of the carrier falls within a range of 10 8 to 10 14 Ωcm.
15. An image forming method comprising the steps of:
forming a latent image on a latent image carrier;
developing the latent image by means of an electrostatic latent image developing toner;
transferring the developed toner image onto a receiver with or without use of an intermediate transfer member; and
fixing the toner image on the receiver by heating and pressurizing; wherein
a fixation device is used for the fixing step, the fixation device comprising rotating members which contact the receiver on front and back sides of the receiver, one of the rotating members being configured in the form of an endless belt, an average nip pressure F of the fixation device during the fixing step being no greater than 2.5 kgf/cm 2 ; and
colorant of the electrostatic latent image developing toner satisfies conditions (a) and (b) below:
(a) an average primary particle size D50 of a quinacridone pigment represented by the above-noted formula (1) and an average primary particle size D50 of a naphthol pigment represented by the above-noted formula (2) are such that the average primary particle size D50 of the quinacridone pigment is smaller than the average primary particle size D50 of the naphthol pigment; and
(b) the average primary particle size D50 of the quinacridone pigment is greater than 20 nm, and the average primary particle size D50 of the naphthol pigment is smaller than 200 nm;
F being given by F=A/D/N, wherein F (kgf/cm 2 ) denotes the average nip pressure during the fixing step, A (kgf) denotes total load applied on the fixation device, D (cm) denotes an average fixation nip width, and N (cm) denotes length of the fixation nip along the axial direction of a roll;
formula (1) being
in which each of R 1 , R 2 , R 3 , and R 4 is selected from the group consisting of H, CH 3 , and Cl; R 1 and R 2 are different from each other; and R 3 and R 4 are different from each other; and
formula (2) being
16. An image forming method as defined in claim 15 , wherein value Gs(60) obtained by measuring, by the 60 degree specular gloss measurement method according to JIS Z 8741, image surface gloss after the fixing step falls within the range of 10 to 60.