Tandem OLED having an organic intermediate connector

1. A tandem OLED comprising:

a) an anode;

b) a cathode;

c) at least two electroluminescent units disposed between the anode and the cathode, wherein each of the electroluminescent units includes at least one hole-transporting layer and one organic light-emitting layer;

d) an intermediate connector disposed between adjacent electroluminescent units, wherein the intermediate connector includes an n-doped organic layer and an electron-accepting layer being disposed closer to the cathode than the n-doped organic layer, wherein the electron-accepting layer has a thickness range of from 3 nm to 100 nm and having one organic material having a molecular weight greater than 350, and having a reduction potential greater than −0.5 V vs. a Saturated Calomel Electrode, and wherein the n-doped organic layer is in direct contact with the electron-accepting layer; and

e) the material in the electron-accepting layer consists of a chemical compound of the following formula:

wherein R 1 -R 6 represent hydrogen or a substituent independently selected from the group including halo, nitrile (—CN), nitro (—NO 2 ), sulfonyl (—SO 2 R), sulfoxide (—SOR), trifluoromethyl (—CF 3 ), ester (—CO—OR), amide (—CO—NHR or —CO—NRR′), substituted or unsubstituted aryl, substituted or unsubstituted heteroaryl, and substituted or unsubstituted alkyl, where R and R′ include substituted or unsubstituted alkyl or aryl; or wherein R 1 and R 2 , R 3 and R 4 , or R 5 , and R 6 combine form a ring structure including an aromatic ring, a heteroaromatic ring, or a nonaromatic ring, and each ring is substituted or unsubstituted.

2. The tandem OLED of claim 1 wherein the organic material has a reduction potential greater than −0.1 V vs. a Saturated Calomel Electrode.

3. The tandem OLED of claim 1 wherein there are three electroluminescent units and two intermediate connectors, each intermediate connector disposed between adjacent electroluminescent units.

4. The tandem OLED of claim 1 wherein the organic material in the electron-accepting layer consists of

5. The tandem OLED of claim 1 wherein the electroluminescent units individually emit red, green, blue, or white light.

6. The tandem OLED of claim 1 wherein the n-type doped organic layer contains one electron-transporting material and at least one n-type dopant.

7. The tandem OLED of claim 6 wherein the electron-transporting material includes metal chelated oxinoid compounds, butadiene derivatives, heterocyclic optical brighteners, triazines, hydroxyquinoline derivatives, benzazole derivatives, phenanthroline derivatives, or silole derivatives, or combinations thereof.

8. The tandem OLED of claim 6 wherein the electron-transporting material includes tris(8-hydroxyquinoline)aluminum (Alq), 4,7-diphenyl-1,10-phenanthroline (Bphen), 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP), or 2,2′-[1,1′-biphenyl]-4,4′-diylbis[4,6-(p-tolyl)-1,3,5-triazine] (TRAZ), or combinations thereof.

9. The tandem OLED of claim 6 wherein the n-type dopant includes alkali metals, alkali metal compounds, alkaline earth metals, alkaline earth metal compounds, or rare earth metal, or combinations thereof.

10. The tandem OLED of claim 6 wherein the n-type dopant includes Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, La, Ce, Nd, Sm, Eu, Tb, Dy, or Yb, or combinations thereof.

11. An OLED solid-state lighting source comprising the tandem OLED of claim 1 .