Electrochemical assembly of organic molecules by the reduction of iodonium salts
View Patent ↗Methods are described for the electrochemical assembly of organic molecules on silicon, or other conducting or semiconducting substrates, using iodonium salt precursors. Iodonium molecules do not assemble on conducting surfaces without a negative bias. Accordingly, the iodonium salts are preferred for patterning applications that rely on direct writing with negative bias. The stability of the iodonium molecule to acidic conditions allows them to be used with standard silicon processing. As a directed assembly process, the use of iodonium salts provides for small features while maintaining the ability to work on a surface and create structures on a wafer level. Therefore, the process is amenable for mass production. Furthermore, the assembled monolayer (or multilayer) is chemically robust, allowing for subsequent chemical manipulations and the introduction of various molecular functionalities for various chemical and biological applications.
1. A method for the electrochemical assembly of iodonium molecules on a surface of a silicon substrate, comprising:
immersing the surface in a solution comprising an iodonium salt precursor; and
applying a negative bias voltage to the surface, thereby causing iodonium molecules to self-assemble on the surface from the solution comprising the iodonium salt precursor.
2. The method of claim 1 , wherein the iodonium salt precursor comprises an aryliodonium salt.
3. The method of claim 1 , wherein the iodonium salt precursor comprises a functional group selected from the group consisting of hydroxyl, nitro, thiol, halogen, ester, amide, perfluoro and hydrocarbon.
4. A method for the electrochemical assembly of iodonium molecules on a surface of a conducting or semiconducting substrate, comprising:
immersing the surface in a solution comprising an iodonium salt precursor;
applying a negative bias voltage to the surface, thereby causing iodonium molecules to self-assemble on the surface from the solution comprising the iodonium salt precursor; and
exposing the assembled iodonium surface to a solution comprising a chemical precursor molecule to react with the assembled iodonium molecules, thereby providing additional functionality to the iodonium surface.
5. The method of claim 4 , wherein the iodonium salt precursor comprises an aryliodonium salt.
6. The method of claim 4 , wherein the iodonium salt precursor comprises a functional group selected from the group consisting of hydroxyl, nitro, thiol, halogen, ester, amide, perfluoro and hydrocarbon.
7. The method of claim 4 , wherein the semiconducting surface comprises silicon.
8. The method of claim 4 , wherein the conducting substrate comprises a metal or carbon.