Planographic printing plate precursor
View Patent ↗A planographic printing plate precursor comprises a support and two or more positive recording layers which are formed on the support, contain a resin and an infrared absorbing agent and exhibit an increase in solubility in an aqueous alkali solution by exposure to infrared laser light, wherein the positive recording layer closest to the support among these two or more positive recording layers contains at least two types of resins among which at least one type forms a dispersion phase. It is preferable that the dispersion phase be formed of (1) a high-polymer compound incompatible with a high-polymer matrix or (2) a granular polymer selected from a microcapsule and a latex, and contains an infrared absorbing agent and an acid generator.
1. A planographic printing plate precursor comprising:
a support; and
two or more positive recording layers which are formed on said support and contain a resin and an infrared absorbing agent and exhibit an increase in solubility in an aqueous alkali solution by exposure to infrared laser light;
wherein the positive recording layer closest to the support among these two or more positive recording layers contains at least two types of resins among which at least one type forms substantially a sphere or flattened sphere dispersion phase.
2. The planographic printing plate precursor of claim 1 , wherein the positive recording layer closest to said support contains a macromolecular compound which is insoluble in water and soluble in an aqueous alkali solution, the macromolecular compound forming a matrix phase.
3. The planographic printing plate precursor of claim 2 , wherein said macromolecular compound forming a matrix phase is incompatible with said resin forming a dispersion phase.
4. The planographic printing plate precursor of claim 2 , wherein said macromolecular compound forming a matrix phase has a functional group selected from a phenolic hydroxyl group, a sulfonamide group, or an active imide group.
5. The planographic printing plate precursor of claim 2 , wherein said resin(s) forming the dispersion phase comprise macromolecules exhibiting strong interaction with each other.
6. The planographic printing plate precursor of claim 5 , wherein said strong interaction is based on hydrogen bonds or ionic bonds between the macromolecules.
7. The planographic printing plate precursor of claim 2 , wherein said resin(s) forming a dispersion phase is selected from a urethane type macromolecular compound, a novolac resin, a diazo resin or a polyether.
8. The planographic printing plate precursor of claim 1 , wherein said infrared absorbing agent is incorporated into said dispersion phase.
9. A planographic printing plate precursor comprising:
a support; and
two or more positive recording layers which are formed on said support and contain a resin and an infrared absorbing agent and exhibit an increase in solubility in an aqueous alkali solution by exposure to infrared laser light;
wherein the positive recording layer closest to the support among these two or more positive recording layers contains at least two types of resins among which at least one type forms a dispersion phase having a maximum size of 0.8 μm or less and an average size of 0.6 μm or less.
10. The planographic printing plate precursor of claim 1 , wherein at least said positive recording layer closest to the support further contains an acid generator or a radical generator.
11. The planographic printing plate precursor of claim 10 , wherein said acid generator or radical generator is incorporated into said dispersion phase.
12. The planographic printing plate precursor of claim 10 , wherein said acid generator or radical generator has high polarity.
13. A planographic printing plate precursor comprising:
a support; and
two or more positive recording layers which are formed on said support and contain a polymer binder and a material which acts on the polymer binder to suppress the solubility of the binder in an aqueous alkali solution, the material losing alkali-solubility suppressing ability thereof on said polymer binder by exposure to infrared laser light;
wherein the positive recording layer closest to the support among these two or more positive recording layers contains another resin(s) different from said polymer binder, at least one of said other resin(s) forming a dispersion phase having a maximum size of 0.8 μm or less and an average size of 0.6 μm or less in a matrix phase formed of said macromolecular weight binder.
14. The planographic printing plate precursor of claim 13 , wherein said polymer binder forming the matrix phase is incompatible with at least one of said other resin(s) forming the dispersion phase.
15. The planographic printing plate precursor of claim 13 , wherein at least one of said other resin(s) forming the dispersion phase comprises macromolecules exhibiting strong interaction with each other.
16. The planographic printing plate precursor of claim 13 , wherein said material suppressing the alkali-solubility of the polymer binder is an infrared absorbing agent.
17. The planographic printing plate precursor of claim 16 , wherein said infrared absorbing agent is incorporated into said dispersion phase.
18. The planographic printing plate precursor of claim 13 , wherein at least said positive recording layer closest to said support further contains an acid generator or a radical generator.
19. The planographic printing plate precursor of claim 18 , wherein said acid generator or radical generator is incorporated into said dispersion phase.