Nano-particulate blends with fully-neutralized ionomeric polymers for golf ball layers
View Patent ↗A golf ball comprising a core, an intermediate layer, and a cover. The core, which has a compression of 100 or less and a diameter of between about 1.00 inches and about 1.64 inches, is formed from a first polymer including an acid group fully-neutralized by a salt of an organic acid, a cation source, or a suitable base of the organic acid; and a nano-material having an average particle size of 100 nm or less, present in an amount sufficient to adjust at least one material property of the first polymer by 5% to 50% when compared to the material property of the first polymer comprising a material identical to the nano-material but having an average particle size greater than 1000 nm. The intermediate layer is formed from a second polymer comprising an acid group fully-neutralized by a salt of an organic acid, a cation source, or a suitable base of the organic acid.
1. A golf ball comprising:
a core comprising:
a first polymer comprising an acid group fully-neutralized by a salt of an organic acid or a suitable base of the organic acid and a sufficient cation source to neutralize the acid groups 100%; and
a nano-material having an average particle size of 100 nm or less, present in an amount sufficient to adjust at least one material property of the first polymer by 5% to 50% when compared to the material property of the first polymer comprising a material identical to the nano-material but having an average particle size greater than 1000 nm;
a cover layer; and
an intermediate layer disposed between the core and the cover layer, the intermediate layer comprising a second polymer comprising an acid group fully-neutralized by a salt of an organic acid or a suitable base of the organic acid and a sufficient cation source to neutralize the acid groups 100%;
wherein the core has a compression of greater than 90 and up to and including 120 and a diameter of between 1.58 inches and 1.64 inches.
2. The golf ball of claim 1 , wherein the material property is selected from the group consisting of density, hardness, moment of inertia, flexural modulus, stiffness modulus, abrasion resistance, heat resistance, impact resistance, water vapor transmission rate, and resilience.
3. The golf ball of claim 1 , wherein the material property of the first polymer is flexural modulus at least 10% to 50% greater than when compared to the flexural modulus of the polymer comprising a material identical to the nano-material and having an average particle size greater than 1000 nm.
4. The golf ball of claim 1 , wherein the material property of the first polymer is hardness at least 5% to 25% greater than when compared to the hardness of the polymer comprising a material identical to the nano-material, the material having an average particle size greater than 1000 nm.
5. The golf ball of claim 1 , wherein the cover layer comprises a polymer selected from the group consisting of ionomeric copolymers and terpolymers, ionomer precursors, thermoplastics, thermoplastic elastomers, polybutadiene rubber, balata, grafted metallocene-catalyzed polymers, non-grafted metallocene-catalyzed polymers, single-site polymers, high-crystalline acid polymers and their ionomers, rosin-modified ionomers, bimodal ionomers, cationic ionomers, anionic ionomers, polyurethanes, and polyureas.
6. The golf ball of claim 1 , wherein the intermediate layer comprises the nano-material having a particle size of 100 nm or less, present in an amount sufficient to adjust at least one material property of the first polymer by 5% to 50% when compared to the material property of the first polymer comprising a material identical to the nano-material but having a particle size greater than 1000 nm.
7. The golf ball of claim 1 , wherein the nano-material comprise swellable layered materials; micaceous minerals; smectite minerals; carbon nanotubes; fullerenes; nanoscale titanium oxides; iron oxides; ceramics; modified ceramics; metal and oxide powders; titanium dioxide particles; single-wall and multi-wall carbon nanotubes; polymer nanofibers; carbon nanofibrils; nitrides; carbides; sulfides; ormocers; glass ionomers; resin-modified glass ionomers; silicon ionomers; polymerizable cements; metal-oxide polymer composites; lipid-based nanotubules, graphite sheets, or polyhedral oligomeric silsequioxanes.
8. The golf ball of claim 7 , wherein the swellable layered material sufficiently sorbs an intercalant polymer to increase the interlayer spacing between adjacent nano-materials to at least about 10 Å.
9. The golf ball of claim 7 , wherein the swellable layered materials comprise phyllosilicates, montmorillonite, sodium montmorillonite; magnesium montmorillonite; calcium montmorillonite; nontronite; beidellite; volkonskoite; hectorite; saponite; sauconite; sobockite; stevensite; svinfordite; or vermiculite.
10. The golf ball of claim 9 , wherein the swellable layered material comprises phyllosilicates having a negative charge ranging from about 0.15 to about 0.9 charges per formula unit and a commensurate number of exchangeable metal cations.
11. The golf ball of claim 1 , wherein the nano-materials are chemically-modified.
12. The golf ball of claim 1 , wherein the cover layer consisting essentially of a polyurethane, a polyurea, a polyurea-urethane, or a polyurethane-urea.
13. The golf ball of claim 1 , wherein a water vapor barrier layer is disposed between the cover and the core.
14. The golf ball of claim 13 , wherein the water vapor barrier layer has a vapor transmission rate of less than 0.45 g-mm 2 -day.
15. The golf ball of claim 1 , wherein the cover comprises a castable polyurea material.