Acceptor compounds useful for making hyperpolarizable organic chromophores
View Patent ↗Acceptor compounds useful for making hyperpolarizable organic chromophores having a π-donor conjugated to a π-acceptor through a π-bridge.
1. A compound having the structure:
wherein R 1 and R 2 are alkyl groups, R 4 a, R 4 b, and R 4 c are independently selected from F, CN, CF 3 , and CF 3 SO 2 , provided that R 4 a, R 4 b, and R 4 c are not all CN.
2. The compound of claim 1 , wherein R 4 a, R 4 b, and R 4 c are independently selected from F, CF 3 , and CF 3 SO 2 .
3. The compound of claim 1 , wherein R 4 a is CN, R 4 b is CN, and R 4 c is CF 3 SO 2 .
4. The compound of claim 1 , wherein R 4 a is CN, R 4 b is CF 3 SO 2 , and R 4 c is CN.
5. The compound of claim 1 , wherein R 4 a is CF 3 SO 2 , R 4 b is CN, and R 4 c is CF 3 SO 2 .
6. The compound of claim 1 , wherein R 4 a is CF 3 SO 2 , R 4 b is CF 3 SO 2 , and R 4 c is CN.
7. The compound of claim 1 , wherein R 4 a, R 4 b, and R 4 c are independently selected from CN, CF 3 , and CF 3 SO 2 .
8. The compound of claim 1 , wherein R 4 a is F, R 4 b is CN, and R 4 c is F.
9. The compound of claim 1 , wherein R 4 a is F, R 4 b is F, and R 4 c is CN.
10. The compound of claim 1 , wherein R 4 a is CF 3 , R 4 b is CN, and R 4 c is CF 3 .
11. The compound of claim 1 , wherein R 4 a is CF 3 , R 4 b is CF 3 , and R 4 c is CN.
12. The compound of claim 1 , wherein R 4 a is CF 3 SO 2 , R 4 b is CF 3 SO 2 , and R 4 c is CF 3 SO 2 .
13. The compound of claim 1 , wherein R 4 a is CN, R 4 b is CF 3 SO 2 , and R 4 c is CF 3 SO 2 .
14. The compound of claim 1 , wherein R 1 and R 2 are methyl.
15. The compound of claim 1 , wherein R 4 a, R 4 b, and R 4 c are F.
16. The compound of claim 1 , wherein R 4 a, R 4 b, and R 4 c are CF 3 .
17. The compound of claim 1 , wherein R 1 and R 2 are methyl and R 4 a, R 4 b, and R 4 c are F.
18. The compound of claim 1 , wherein R 1 and R 2 are methyl and R 4 a, R 4 b, and R 4 c are CF 3 .