Property recovering method
View Patent ↗A method is disclosed for recovering the properties of single crystal and directionally solidified Nickel based superalloys and articles made thereof, after use in a high temperature environment. The method comprises the steps of a stress relief treatment, a γ′ rejuvenation heat treatment at a temperature below the γ′-solvus temperature (T solvus, γ′ ) of the superalloy, a precipitation heat treatment and an aging heat treatment.
1. A property recovering method for single crystal and directionally solidified material bodies made from a Nickel based superalloy with a degraded and rafted microstructure comprising the steps of
(a) a stress relief treatment at 850° C.-1100° C.,
(b) a γ′ rejuvenation treatment at a temperature of 20° C. to 80° C. below γ′-solvus temperature of the Nickel based superalloy,
(c) a precipitation treatment at 1050° C.-1150° C. and
(d) an aging heat treatment at 800° C.-980° C.
2. The method according to claim 1 , wherein the stress relief heat treatment is applied to an article made at least in part with a material which is essentially composed of, in weight percent, 9.3-10% Co, 6.4-6.8% Cr, 0.5-0.7% Mo, 6.2-6.6% W, 6.3-6.7% Ta, 5.45-5.75% Al, 0.8-1.2% Ti, 0-0.3% Hf, 2.8-3.2% Re, the rest nickel and unavoidable impurities, and stress the relief treatment is carried out at a temperature of about 950° C. for 1 to 4 hours and at about 1050° for 2 to 20 hours.
3. The method according to claim 1 , wherein the γ′ solvus temperature is determined by performing Differential Thermal Analysis measurements on the service-exposed and degraded alloy and observing the temperature of the onset of γ′ solutioning and the γ′ solvus temperature.
4. The method according to claim 1 , wherein the heat treatment is applied to an article made at least in part with a material which is essentially composed of, in weight percent, 9.3-10% Co, 6.4-6.8% Cr, 0.5-0.7% Mo, 6.2-6.6% W, 6.3-6.7% Ta, 5.45-5.75% Al, 0.8-1.2% Ti, 0-0.3% Hf, 2.8-3.2% Re, the rest nickel and unavoidable impurities, the γ′ rejuvenation heat treatment is carried out at a temperature between 1220° C. to 1270° C. for 2 to 12 hours.
5. The method according to claim 4 , wherein the γ′ rejuvenation treatment is carried out at a temperature between 1220° C. and 1250° C. for 2 to 12 hours.
6. The method according to claim 1 , wherein recrystallized areas are detected after the γ′ rejuvenation heat treatment and the recrystallized material is replaced by welding or insert brazing a replacement coupon.
7. The method according to claim 6 , wherein the replacement coupon is welded epitaxially with base material.
8. The method according to claim 7 , wherein the replacement coupon material to be brazed is of a single crystal or directionally solidified structure similar to the base material and the brazing solidifies epitaxially with the coupon and base material.
9. A method of heat treating a nickel-based superalloy comprising a γ′ phase, a γ′ solvus temperature, and a degraded and rafted microstructure, the method comprising:
(i) determining the γ′ solvus temperature of the superalloy;
(ii) treating the superalloy at 850° C.-1100° C.
(iii) treating the superalloy at 20° C.-80° C. below the γ′ solvus temperature;
(iv) treating the superalloy at 1050° C.-1150° C.; and
(v) treating the superalloy at 800° C.-980° C.
10. The method of claim 9 , wherein (iii) is performed at about 1220° C.-1270° C. for 2-12 hours.
11. The method of claim 9 , wherein (i) is performed using differential thermal analysis.
12. The method of claim 9 , wherein (ii) is performed for 3-24 hours.
13. The method of claim 12 , wherein (ii) is performed at about 950° C. for 1-4 hours, and at 1050° C. for 2-20 hours.