Oxidation catalyst on a substrate utilized for the purification of exhaust gases
View Patent ↗An oxidation catalyst deposited on a filter substrate for the removal of CO, hydrocarbons, and particulate matter, such as soot, from an exhaust stream wherein the oxidation catalyst is formed from a platinum group metal supported on a refractory oxide, tin oxide, and a zeolite.
1. An oxidation catalyst deposited on a substrate, for the removal of CO, hydrocarbons, and particulate matter from an exhaust stream, wherein the oxidation catalyst comprises
a platinum group metal supported on the following components:
a refractory oxide;
tin oxide; and
a zeolite,
wherein the refractory oxide comprises at least 5% of the oxidation catalyst and wherein the tin oxide comprises at least about 5% of the oxidation catalyst.
2. The oxidation catalyst of claim 1 wherein the platinum group metal is selected from the group consisting of platinum, palladium, rhodium and mixtures thereof.
3. The oxidation catalyst of claim 1 wherein a precursor material for the platinum group metal produces negative ions when blended in an aqueous solution.
4. The oxidation catalyst of claim 1 wherein a precursor material for the platinum group metal is selected from the group consisting of platinum sulfite acid, ammonium platinum sulfite, dihydrogen hexahydroxyplatinate, hydrogen tetranitroplatinate, hydrogen dinitrosulphatopalladate, hydrogen tetranitropalladate, hydrogen hexanitrorhodate, and mixtures thereof.
5. The oxidation catalyst of claim 1 wherein the zeolite is selected from the group consisting of ZSM-5, beta-zeolite, mordenite, Y-zeolite, ferrierite and mixtures thereof.
6. The oxidation catalyst of claim 1 wherein the platinum group metal is substantially not secured within cages of the zeolite structure.
7. The oxidation catalyst of claim 1 wherein the refractory oxide is selected from the group consisting of alumina, silica, titania, zirconia, silica-alumina, alumina- zirconia, alumina-titania, silica-titania, silica-zirconia, titania-zirconia and mixtures thereof.
8. The oxidation catalyst of claim 1 wherein the refractory oxide is modified by blending with a material selected from rare earth metal oxides, tungstic oxide and mixtures thereof.
9. The oxidation catalyst of claim 8 wherein the rare earth metal oxide is selected from lanthanum oxide, cerium oxide, yttrium oxide and mixtures thereof.
10. The oxidation catalyst of claim 1 wherein the refractory oxide comprises a lanthanum oxide activated alumina.
11. The oxidation catalyst of claim 1 wherein the tin oxide is precalcinated at a temperature from about 600 C to about 1000 C prior to formation of the oxidation catalyst.
12. The oxidation catalyst of claim 1 wherein the tin oxide substantially comprises tin oxide particles with a particle size from 30-100 micrometers.
13. The oxidation catalyst of claim 1 wherein the substrate comprises a honeycomb or a monolithic structure.
14. The oxidation catalyst of claim 1 wherein the substrate is produced from the group consisting of cordierite, mullite, iron-chromium alloy and stainless steel.
15. The oxidation catalyst of claim 1 wherein the platinum group metal comprises from about 0.01 to about 20 percent by weight of the oxidation catalyst.
16. The oxidation catalyst of claim 1 wherein the zeolite comprises from about 10% to about 80%, by weight of the oxidation catalyst.
17. The catalyst of claim 1 wherein the refractory metal oxide comprises from about 5 to about 90 percent by weight of the oxidation catalyst.
18. The oxidation catalyst of claim 1 wherein tin oxide comprises 5 to about 80 percent by weight of the oxidation catalyst.
19. An oxidation catalyst deposited on a substrate, for the removal of CO, hydrocarbons and particulate matter from a diesel exhaust stream, wherein the oxidation catalyst comprises
a platinum group metal supported on the following components:
a refractory oxide, wherein the refractory oxide is modified by blending with a rare earth oxide;
tin oxide with a particle size from 30-100 micrometers; and
a zeolite,
wherein the refractory oxide comprises at least 5% of the oxidation catalyst and wherein the tin oxide comprises at least about 5% of the oxidation catalyst.
20. A process for the production of an oxidation catalyst deposited on a substrate for the removal of CO, hydrocarbons and particulate matter from an exhaust stream comprising
preparing an aqueous mixture of a refractory oxide, tin oxide and a zeolite;
blending the mixture;
coating a substrate with the blended mixture;
drying and calcining the coated substrate;
depositing a platinum group metal precursor material on the calcined coated substrate; and
calcining the platinum group metal coated substrate, wherein the refractory oxide comprises at least 5% of the oxidation catalyst and wherein the tin oxide comprises at least about 5% of the oxidation catalyst.
21. The process of claim 20 wherein the aqueous mixture is blended with a binder selected from the group consisting of colloidal alumina, colloidal silica, titania, zirconia, ceria and mixtures thereof.
22. A process for the production of an oxidation catalyst deposited on a substrate for the removal of CO, hydrocarbons and particulate matter from an exhaust stream comprising
preparing an aqueous mixture of a refractory oxide, tin oxide with a particle size from 30-100 micrometers, zeolite and a platinum group metal precursor material;
blending the mixture;
coating a substrate with a blended mixture; and
drying and calcining the coated substrate,
wherein the refractory oxide comprises at least 5% of the oxidation catalyst and wherein the tin oxide comprises at least about 5% of the oxidation catalyst.
23. The process of claim 22 wherein the aqueous mixture is blended with a binder selected from the group consisting of colloidal alumina, colloidal silica, titania, zirconia ceria and mixtures thereof.