Golf ball with vapor barrier layer and method of making same
View Patent ↗A golf ball with at least one moisture vapor barrier layer is disclosed. In accordance to one aspect of the invention, the moisture vapor barrier layer may comprise butyl rubber. The butyl rubber may also be a halogenated butyl rubber such as bromobutyl rubber or chlorobutyl rubber. The butyl rubber may also be a sulfonated butyl rubber. The butyl rubber may be blended with other polymers. In accordance to another aspect of the invention, the moisture vapor barrier layer is placed on to a core subassembly and cured by infrared radiation (IR). IR-curable moisture vapor barrier materials include, but not limited to, butyl rubber, polysulfide rubber and single-pack castable polymers, among others. In accordance to another aspect of the invention, an outer layer of the golf ball may comprise a polymer that has a cured temperature greater than the softening temperature or melting temperature of the encased subassembly. Such outer layer may be cured by IR. The outer layer may be a cover, an intermediate layer or a moisture vapor barrier layer.
1. A golf ball comprising a cover layer encasing a subassembly, the subassembly comprising a moisture vapor barrier layer encasing a core, wherein the moisture vapor barrier layer has a moisture vapor transmission rate of less than about 0.6 grams·mm/m 2 ·day, and is formed from a composition comprising an elastomer and a double-bond vulcanizable rubber, and a thickness of less than 0.01 inch, wherein the composition is cured by infra red radiation or a combination of infra red and ultra violet radiations such that the properties of the core remain unchanged after curing of the moisture vapor barrier layer.
2. The golf ball of claim 1 , wherein the elastomer is halogenated, sulfonated, or both.
3. The golf ball of claim 2 , wherein the elastomer is halogenated, and comprises at least one of the following:
less than about 3% reactive halogen;
less than about 1 halogen atom per double bond;
a benzylic bromine functionality; or
a branched styrenic block.
4. The golf ball of claim 1 , wherein the elastomer comprises a conjugated multi-olefin or an iso-olefin.
5. The golf ball of claim 1 , wherein the elastomer is a copolymer of p-methylstyrene and isobutylene or a brominated copolymer of p-methylstyrene and isobutylene.
6. The golf ball of claim 1 , wherein the composition further comprises a filler.
7. The golf ball of claim 6 , wherein the filler is selected from a group consisting of leafing aluminum, mica flakes, micaceous iron oxide flakes, aluminum flakes, ceramic flakes, graphite flakes, and mixtures thereof.
8. The golf ball of claim 1 , wherein the composition further comprises at least one polymer selected from a group consisting of vinyldiene chloride polymers and ionomers.
9. The golf ball of claim 1 , wherein the composition has a moisture vapor transmission rate of about 0.001 grams·mm/m 2 ·day to about 0.1 grams·mm/m 2 ·day.
10. The golf ball of claim 1 , wherein the composition is a dynamically vulcanizable thermoplastic elastomer blend adhesive to diene rubbers.
11. The golf ball of claim 1 , wherein the elastomer has a molecular weight of about 20,000 to about 500,000.
12. The golf ball of claim 1 , wherein the composition forms a tortuous path against moisture vapor encroachment.
13. The golf ball of claim 1 , wherein the composition is applied in a form selected from a group consisting of liquid, latex, viscous liquid, semi-solid, solid, and in solvents.
14. A golf ball comprising a cover layer encasing a subassembly, the subassembly comprising a moisture vapor barrier layer encasing a core, wherein the moisture vapor barrier layer has a moisture vapor transmission rate of less than about 0.6 grams·mm/m 2 ·day, a thickness of less than 0.01 inch, and is formed from a composition comprising an elastomeric homopolymer or copolymer that comprises about 0.2% to about 30% by weight of a conjugated multi-olefin having about 4 to about 14 carbon atoms, an iso-olefin having greater than 4 to about 7 carbon atoms, or a combination of the conjugated multi-olefin and the iso-olefin, and wherein the composition is cured by infra red radiation or a combination of infra red and ultra violet radiations, and wherein the materials comprising the moisture vapor barrier layer have higher cured temperatures than the softening temperatures of the materials comprising the core.
15. The golf ball of claim 14 , wherein the elastomeric copolymer comprises the conjugated multi-olefin and about 70% to about 99.8% by weight of the iso-olefin.
16. The golf ball of claim 14 , wherein the elastomeric homopolymer or copolymer is amorphous and non-polar.
17. The golf ball of claim 14 , wherein the elastomeric homopolymer or copolymer is sulfonated, halogenated, or both; and wherein when halogenated, the elastomeric homopolymer or copolymer comprises at least one of the following:
less than about 3% reactive halogen,
less than about 1 halogen atom per double bond,
a benzylic bromine functionality, or
a branched styrenic block.
18. The golf ball of claim 14 , wherein the elastomeric homopolymer or copolymer is a highly paraffinic hydrocarbon polymer composed on long straight chain molecules containing only chain-end olefinic bonds.
19. The golf ball of claim 14 , wherein the elastomeric copolymer is a copolymer of p-methylstyrene and isobutylene or a brominated copolymer of p-methylstyrene and isobutylene.
20. The golf ball of claim 14 , wherein the composition forms a tortuous path against moisture vapor encroachment.
21. The golf ball of claim 14 , wherein the composition is applied in a form selected from a group consisting of liquid, latex, viscous liquid, semi-solid, solid, and in solvents.
22. The golf ball of claim 14 , wherein the composition further comprises a filler selected from a group consisting of leafing aluminum, mica flakes, micaccous iron oxide flakes, aluminum flakes, ceramic flakes, graphite flakes, and mixtures thereof.