IP Library Granted Patent US 7,411,025
Granted Patent B1
US 7,411,025 · App. 11/084,118 · Granted Aug 12, 2008

Cure accelerators for anaerobic curable compositions

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Quick Facts
Patent No.
US 7,411,025
App. No.
11/084,118
Granted
Aug 12, 2008
Kind
B1
Abstract

The present invention relates to phenylgycines and derivatives thereof, 1,4-aminobenzoyl compounds, and phenyl pyrazolinones as cure accelerators for anaerobically curable compositions.

Claims (14)

1. An anaerobic curable composition, comprising:

(a) a (meth)acrylate component; and

(b) an anaerobic cure-inducing composition comprising an anaerobic cure accelerator compound within structure I

wherein R appears up to five times on the phenyl ring and is independently selected from the group consisting of hydrogen, halogen, alkenyl, hydroxyalkyl, hydroxyalkenyl, or sulfonato; R 1 is selected from the group consisting of hydrogen, alkyl, alkenyl, hydroxyalkyl, hydroxyalkenyl, aralkyl, carbonyl or carboxyl; and R 2 is selected from the group consisting of hydrogen, alkyl, alkenyl, hydroxyalkyl, hydroxyalkenyl, aralkyl, nitrogen, carbonyl and carboxyl.

2. The composition according to claim 1 , wherein the (meth)acrylate component is represented by H 2 C═CGCO 2 R 1 , wherein G is a member selected from the group consisting of H, halogen and alkyl having from 1 to about four carbon atoms, and R 1 is a member selected from the group consisting of alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkaryl, and aryl groups having from 1 to about 16 carbon atoms, with or without substitution or interruption by a member selected from the group consisting of silane, silicon, oxygen, halogen, carbonyl, hydroxyl, ester, carboxylic acid, urea, urethane, carbamate, amine, amide, sulfur, sulonate and sulfone.

3. The composition according to claim 1 , wherein the (meth)acrylate component is a member selected from the group consisting of silicone (meth)acrylates, polyethylene glycol di(meth)acrylates, bisphenol-A-(meth)acrylates, ethoxylated bisphenol-A-(meth)acrylates, bisphenol-F-(meth)acrylates, ethoxylated bisphenol-F-(meth)acrylates, tetrahydrofuran (meth)acrylates and di(meth)acrylates, hydroxypropyl (meth)acrylate, hexanediol di(meth)acrylate, and trimethylol propane tri(meth)acrylate.

4. The composition according to claim 1 , wherein the anaerobic cure accelerator is a member selected from the group consisting of N-phenyl glycine, N-methyl-N-phenyl glycine, ethyl-4-(dimethylamino) benzoate, and combinations thereof.

5. The composition according to claim 1 , further comprising an additional accelerator.

6. The composition according to claim 1 , further comprising a peroxide compound.

7. The composition according to claim 5 , wherein the additional accelerator is saccharin.

8. A method of preparing an anaerobic curable composition, comprising the step of:

mixing together:

a (meth)acrylate component, and

an anaerobic cure inducing composition comprising an anaerobic cure accelerator compound in accordance with claim 1 .

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 26, 2015
From: HENKEL US IP LLC
To: HENKEL IP & HOLDING GMBH
Reel/Frame 035100/0151 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 7, 2014
From: HENKEL CORPORATION
To: HENKEL US IP LLC
Reel/Frame 034183/0611 →