Manufacturing method of photothermographic material and photothermographic material
A method of manufacturing a photothermographic material that has at least on one surface of a support an image-forming layer that includes at least photosensitive silver halide, non-photosensitive organic silver salt, a reducing agent and a binder, wherein 1) the non-photosensitive organic silver salt is dispersed with at least one dispersing agent selected from polyvinyl alcohol having an average polymerization degree of 1,500 or less; a surfactant; and gelatin; and 2) the pH of a coating solution of the image-forming layer is 4 or more and 8.2 or less; and a photothermographic material manufactured according to the manufacturing method thereof.
1 . A method of manufacturing a photothermographic material that has on at least one surface of a support an image-forming layer that includes at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder, wherein:
the non-photosensitive organic silver salt is dispersed with at least one dispersing agent selected from polyvinyl alcohol having an average polymerization degree of 1,500 or less, a surfactant, and gelatin; and
the pH of a coating solution of the image-forming layer is 4 or more and 8.2 or less.
2 . The method of manufacturing a photothermographic material according to claim 1 , wherein the surfactant is a nonionic surfactant.
3 . The method of manufacturing a photothermographic material according to claim 1 , wherein the surfactant is an anionic surfactant.
4 . The method of manufacturing a photothermographic material according to claim 1 , wherein the surfactant is a cationic surfactant.
5 . The method of manufacturing a photothermographic material according to claim 1 , wherein the surfactant is an amphoteric surfactant.
6 . The method of manufacturing a photothermographic material according to claim 1 , wherein the pH of the coating solution of the image forming layer is 4 or more and 8 or less.
7 . The method of manufacturing a photothermographic material according to claim 1 , wherein the gelatin is acid-processed gelatin.
8 . The method of manufacturing a photothermographic material according to claim 1 , wherein an aqueous solvent is used to coat the image forming layer.
9 . The method of manufacturing a photothermographic material according to claim 1 , wherein 50 mass percent or more of the binder is polymer latex.
10 . The method of manufacturing a photothermographic material according to claim 9 , wherein the polymer latex includes a monomer component having an acid group in an amount of 1 mass percent or more and 20 mass percent or less.
11 . The method of manufacturing a photothermographic material according to claim 9 , wherein the glass transition point (Tg) of the polymer latex is −10 degrees centigrade or more and 70 degrees centigrade or less.
12 . The method of manufacturing a photothermographic material according to claim 1 , wherein the pH of the coating solution is 6 or more and 8 or less.
13 . The method of manufacturing a photothermographic material according to claim 1 , wherein an amount of coated silver is 0.5 g/m 2 or more and 1.6 g/m 2 or less.
14 . The method of manufacturing a photothermographic material according to claim 1 , wherein the non-photosensitive organic silver salt is a needle crystal.
15 . The method of manufacturing a photothermographic material according to claim 14 , wherein, when a needle-shaped grain of the non-photosensitive organic silver salt is approximated to a rectangle and side lengths thereof are defined as a, b and c from a shortest side to a longest side, a ratio of c/b is 10 or more and 500 or less.
16 . The method of manufacturing a photothermographic material according to claim 1 , wherein a behenate content of the non-photosensitive organic silver salt is 90 mol percent or more and 99 mol percent or less.
17 . The method of manufacturing a photothermographic material according to claim 1 , wherein the saponification degree of the polyvinyl alcohol is in the range of 80 to 92 percent.
18 . A photothermographic material manufactured according to a manufacturing method of a photothermographic material of claim 1 , that has on at least one surface of a support an image-forming layer that includes at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder, wherein:
the non-photosensitive organic silver salt is dispersed with at least one dispersing agent selected from polyvinyl alcohol having an average polymerization degree of 1,500 or less, a surfactant, and gelatin, and
the pH of a coating solution of the image-forming layer is 4 or more and 8.2 or less.
19 . The photothermographic material according to claim 18 , further comprising a development accelerator.
20 . The photothermographic material according to claim 18 , further comprising a hydrogen-bonding compound.