Fine structural body and method of producing the same
View Patent ↗Described is a structural body including at least partially an aluminum member having on a surface an anodized film with micropores present, in which: the micropores have a coefficient of variation in pore size of 5 to 50%; and the micropores are each sealed with a metal. The structural body can generate localized plasmon resonance having a sufficiently large intensity and be produced at low cost through a simple production process, and having a large surface area.
1. A structural body including at least partially an aluminum member having on a surface an anodized film with micropores present, in which: the micropores have a coefficient of variation in pore size of 5 to 50%; and the micropores are each sealed with a metal; the anodized film has a thickness of 0.1 to 1 μm; the micropores have an average pore size of 0.01 to 0.5 μm and an average pore density of 50 to 150 pores/μm 2 ; the micropores collectively account for an area ratio of 20 to 50%; and the structural body has a surface porosity of 20% or less.
2. The structural body according to claim 1 , in which the metal is present on the surface of the anodized film as particles.
3. The structural body according to claim 1 , in which a surface of the anodized film has a surface property selected from hydrophilic property and hydrophobic property.
4. The structural body according to claim 1 , in which the metal is one of a single particle and an aggregate and is produced through one of an electrodeposition method and a method involving applying a dispersion liquid of metal particles and drying the applied liquid.
5. The structural body according to claim 1 , in which the aluminum member has an aluminum purity of 99.5 wt % or more.
6. The structural body according to claim 1 , in which the metal is one of gold and silver.
7. The structural body according to claim 1 , in which the metal is a magnetic metal.
8. The structural body according to claim 7 , in which the magnetic metal is one of a single substance and an alloy of at least one element selected from the group consisting of Fe, Co, and Ni.
9. A method of producing the structural body according to claim 1 , including the steps of: forming pits on a surface of the aluminum member; subjecting the aluminum member to anodizing treatment for forming the anodized film having the micropores at positions of the pits; and filling the metal into the micropores for sealing.
10. The method of producing a structural body according to claim 9 , in which the step of forming pits on a surface of the aluminum member is conducted through anodizing treatment.
11. The method of producing a structural body according to claims 10 , in which, in the step of forming pits on a surface of the aluminum member, the anodized film formed through the anodizing treatment has a thickness of 10 to 50 μm.
12. A sample holder for Raman spectroscopic analysis comprising the structural body according to claim 1 .
13. A magnetic recording medium comprising the structural body according to claim 7 .