Hyperplaty clays and their use in paper coating and filling, methods for making same, and paper products having improved brightness
View Patent ↗The present invention relates to a hydrous kaolin product having improved optical properties, for example, when used in the production of paper products. The present invention comprises an improved barrier coating for paper and a method of making the coated paper. The present invention also comprises an improved method from making filled and coated paper products. The present invention uses a composition comprising kaolin having a shape factor of at least about 70:1, such as at least about 80:1 or at least about 100:1.
1. A method of refining kaolin, comprising:
providing a kaolin slurry;
attrition grinding the kaolin slurry;
removing a coarse particle size fraction from the slurry by centrifugation; and
attrition grinding the coarse-particle size fraction to provide a kaolin product having a shape factor of at least about 70:1.
2. The method according to claim 1 , wherein the kaolin slurry comprises whole crude kaolin or a blend of whole crude and coarse-particle size fractions from a centrifuge.
3. The method according to claim 1 , wherein the kaolin product has a shape factor ranging from about 70:1 to about 140:1.
4. The method according to claim 1 , wherein the kaolin product has a shape factor ranging from about 80:1 to about 100:1.
5. The method according to claim 1 , wherein the kaolin slurry is beneficiated prior to the attrition grinding.
6. The method according to claim 1 , wherein the kaolin slurry is degritted prior to the attrition grinding.
7. The method according to claim 1 , wherein the kaolin slurry comprises a blunged-degritted-brightness beneficiated slurry.
8. The method according to claim 1 , wherein the coarse particle size fraction that is removed comprises kaolin particles comprising from 80% to 95% by weight of the particles having an esd of less than 2 μm.
9. The method according to claim 1 , wherein the kaolin product resulting from attrition grinding the coarse particle size fraction comprises particles having an esd ranging from 0.2 μm to 1.7 μm.
10. The method according to claim 1 , wherein the kaolin product resulting from attrition grinding the coarse particle size fraction comprises particles having a shape factor value ranging from 80:1 to 110:1.
11. The method according to claim 1 , wherein the kaolin product has a shape factor of at least about 80:1.
12. The method according to claim 1 , wherein the kaolin product has a shape factor of at least about 90:1.
13. The method according to claim 1 , wherein the kaolin product has a shape factor of at least about 100:1.