Method of in situ retrieval of contaminants or other substances using a barrier system and leaching solutions

1. A method of treating a zone of interest, comprising:

constructing an impermeable barrier to substantially contain the zone of interest, constructing an impermeable barrier including extending at least a portion of the impermeable barrier beneath at least a portion of the zone of interest;

generating a restricted flow of effluent through the zone of interest by introducing a treatment solution to the zone of interest;

providing at least one treatment solution introduction source constructed to introduce the treatment solution to the zone of interest; and

collecting effluent from the zone of interest through at least one removal pipe to remediate a contaminant therein.

2. The method according to claim 1 , wherein providing at least one treatment solution introduction source comprises emplacing an injection well within the zone of interest.

3. The method according to claim 1 , wherein introducing a treatment solution to the zone of interest comprises applying a treatment solution to a surface of ground above the zone of interest, allowing the treatment solution to flow therethrough.

4. The method according to claim 1 , wherein introducing a treatment solution to the zone of interest comprises at least one of flowing the treatment solution into the zone of interest through at least one feed pipe inserted into the zone of interest or introducing the treatment solution to the zone of interest by way of the impermeable barrier.

5. The method according to claim 1 , wherein introducing a treatment solution to the zone of interest comprises providing a solution comprising at least one component selected from the group consisting of a biological treatment agent, nutrients for a biological treatment agent, a detergent, an alcohol, water, hydrogen peroxide, an iodine solution, an oxylating complex and a chelating agent.

6. The method according to claim 5 , wherein introducing a treatment solution comprising a chelating agent comprises providing a solution comprising at least one component selected from the group consisting of EDTA and EGTA.

7. The method according to claim 1 , wherein introducing a treatment solution to the zone of interest comprises providing an acidic solution comprising nitric acid, hydrofluoric acid, hydrochloric acid or a mixture thereof.

8. The method according to claim 1 , wherein introducing a treatment solution to the zone of interest comprises introducing a gas containing treatment solution.

9. The method according to claim 1 , further comprising constructing an essentially airtight cap connected to the impermeable barrier to substantially contain the zone of interest.

10. The method according to claim 1 , wherein constructing an impermeable barrier to substantially contain the zone of interest comprises constructing a barrier comprising a plurality of casings collectively defining a continuous barrier, each of the casings connected to an adjacent casing via at least one interlock structure.

11. The method according to claim 10 , wherein constructing a barrier comprising a plurality of casings collectively defining a continuous barrier, each of the casings connected to an adjacent casing via an interlock formed by the at least one interlock structure comprises forming a seal between adjacent casings by disposing a sealant proximate the interlock.

12. The method according to claim 1 , further comprising recovering and recycling treatment solution collected through the at least one treatment solution introduction source.

13. A method of treating a zone of interest, comprising:

isolating a zone of interest, wherein said isolation comprises constructing an impermeable barrier to isolate at least a portion of the zone of interest, constructing an impermeable barrier including extending at least a portion of the impermeable barrier beneath at least a portion of the zone of interest;

providing at least one treatment solution introduction source and at least one effluent removal source to the isolated zone of interest;

introducing a treatment solution to the isolated zone of interest through the at least one treatment solution introduction source, wherein the introduction of the treatment solution generates a restricted flow of an effluent through the isolated zone of interest; and

collecting at least a portion of the restricted flow of the effluent from the isolated zone of interest at the at least one effluent removal source.

14. The method according to claim 13 , wherein constructing an impermeable barrier to isolate at least a portion of the zone of interest comprises constructing an impermeable barrier layer around the entire zone of interest.

15. The method according to claim 13 , wherein isolating a zone of interest further comprises isolating at least a portion of the zone of interest with a trench.

16. The method according to claim 13 , wherein providing at least one treatment solution introduction source comprises emplacing at least one injection well within the isolated zone of interest.

17. The method according to claim 13 , wherein introducing a treatment solution to the isolated zone of interest comprises introducing a solution comprising at least one component selected from the group consisting of a biological treatment agent, a nutrient for a biological treatment agent, a detergent, an alcohol, a gas, water, hydrogen peroxide, an iodine solution, an oxylating complex, a chelating agent, EDTA, EGTA, an acidic solution, nitric acid, hydrofluoric acid, and hydrochloric acid.

18. The method according to claim 13 , wherein constructing an impermeable barrier to isolate at least a portion of the zone of interest comprises constructing a impermeable barrier comprising a plurality of casings, wherein each of the plurality of casings is connected to an adjacent casing by at least one interlock structure.

19. The method according to claim 18 , further comprising disposing a sealant proximate to each of the at least one interlock structures.