Flame retardant composition
View Patent ↗A flame retardant additive composition comprising a phosphoric acid salt selected from the group consisting of melamine phosphate, melamine pyrophosphate, melamine orthophosphate, diammonium phosphate, monoammonium phosphate, phosphoric acid amide, melamine polyphosphate, ammonium polyphosphate, polyphosphoric acid amide and combinations of two or more of the foregoing; a metal hydroxide; and an organic phosphate. The flame retardant additive is useful in a wide range of thermoplastic compositions.
1. A flame retardant additive composition comprising:
10 to 40 weight percent of a phosphoric acid salt selected from the group consisting of melamine phosphate, melamine pyrophosphate, melamine orthophosphate, diammonium phosphate, monoammonium phosphate, phosphoric acid amide, melamine polyphosphate, ammonium polyphosphate, polyphosphoric acid amide and combinations of two or more of the foregoing;
10 to 45 weight percent of a metal hydroxide; and
15 to 80 weight percent of an organic phosphate, wherein all amounts are based on the total weight of the fire retardant additive composition.
2. The composition of claim 1 wherein the organic phosphate is selected from the group consisting of tris(butyl phenyl) phosphate, resorcinol bis-diphenylphosphate, bis-phenol A bis-diphenylphosphate, triphenyl phosphate, tris(isopropyl phenyl) phosphate, and combinations of two or more of the foregoing; the phosphoric acid salt is melamine polyphosphate; and the metal hydroxide is selected from the group consisting of magnesium hydroxide, aluminum hydroxide, cobalt hydroxide and combinations of two or more of the foregoing.
3. The composition of claim 1 further comprising a diluent material.
4. A covered wire comprising the composition of claim 1 .
5. A flame retardant thermoplastic composition comprising:
a thermoplastic resin;
10 to 45 weight percent of a phosphoric acid salt selected from the group consisting of melamine phosphate, melamine pyrophosphate, melamine orthophosphate, diammonium phosphate, monoammonium phosphate, phosphoric acid amide, melamine polyphosphate, ammonium polyphosphate, polyphosphoric acid amide and combinations of two or more of the foregoing;
10 to 45 weight percent of a metal hydroxide; and
15 to 80 weight percent of an organic phosphate, wherein the weight percents are based on the combined weight of the phosphoric acid salt, metal hydroxide, and organic phosphate.
6. The flame retardant thermoplastic composition of claim 5 wherein the thermoplastic resin is selected from the group consisting of poly(arylene ether), poly(arylene ether) blends, styrenic polymers and copolymers and their blends, polyolefin, polyolefin blends, polyethers and their blends, polyamides and their blends.
7. The flame retardant thermoplastic composition of claim 6 wherein the poly(arylene ether) blend is selected from the group consisting of compatibilized poly(arylene ether)/polyamide, poly(arylene ether)/polyolefin, poly(arylene ether)/olefinic thermoplastics vulcanizates, poly(arylene ether)/ethylene-propylene rubber, poly(arylene/ether)/EPDM, poly(arylene ether)/styrenic polymer, poly(arylene ether)/styrenic copolymer, impact modified poly(arylene ether) and poly(arylene ether)/thermoplastic polyurethane.
8. The flame retardant thermoplastic composition of claim 5 wherein the organic phosphate is selected from the group consisting of tris(butyl phenyl) phosphate, resorcinol bis-diphenylphosphate, bis-phenol A bis-diphenylphosphate, triphenyl phosphate, tris(isopropyl phenyl) phosphate and mixtures of two or more of the foregoing; the phosphoric acid salt is melamine polyphosphate; and the metal hydroxide comprises magnesium hydroxide, aluminum hydroxide, cobalt hydroxide and combinations of two or more of the foregoing.
9. The composition of claim 8 wherein the metal hydroxide comprises magnesium hydroxide.
10. A flame retardant thermoplastic composition comprising:
poly(arylene ether);
an impact modifier;
a polyolefin;
10 to 40 weight percent of a phosphoric acid salt selected from the group consisting of melamine phosphate, melamine pyrophosphate, melamine orthophosphate, diammonium phosphate, monoammonium phosphate, phosphoric acid amide, melamine polyphosphate, ammonium polyphosphate, polyphosphoric acid amide and combinations of two or more of the foregoing;
10 to 45 weight percent of a metal hydroxide; and
15 to 80 weight percent of an organic phosphate, wherein the phosphoric acid salt, metal hydroxide and organic phosphate amounts are based on the combined weight of the phosphoric acid salt, metal hydroxide and organic phosphate.
11. The composition of claim 10 wherein the impact modifier comprises a combination of a first block copolymer having a styrene content of 10 weight percent to 20 weight percent based on the total weight of the first block copolymer and a second block copolymer having a styrene content of 25 weight percent to 50 weight percent based on the total weight of the second block copolymer.
12. The composition of claim 10 wherein the impact modifier comprises a block copolymer comprising an aryl alkene block and a controlled distribution copolymer block.
13. The composition of claim 10 wherein the composition has a Shore A hardness, as determined by ASTM D 2240, of 75 to 95; a Shore D hardness, as determined by ASTM D 2240, of 20 to 60; and a flexural modulus, as determined by ASTM D790 using bars with a thickness of 6.4 millimeters, of less than or equal to 1172 megapascals.
14. The composition of claim 10 wherein the impact modifier comprises a polystyrene-poly(ethylene-butylene)-polystyrene block copolymer.
15. The composition of claim 10 wherein the composition has a tensile strength greater than or equal to 7.0 megapascals and a tensile elongation greater than or equal to 100% and further wherein tensile strength and tensile elongation are determined by ASTM D638.
16. The composition of claim 15 wherein the tensile elongation is greater than or equal to 300%.
17. The composition of claim 10 wherein the composition has a flame retardancy rating, according to UL94, of V2 or better.
18. The composition of claim 10 wherein the poly(arylene ether) is present in an amount of 10 to 65 weight percent, the impact modifier is present in an amount of 5 to 50 weight percent, the polyolefin is present in an amount of 5 to 50 weight percent and the combination of phosphoric acid salt, metal hydroxide and organic phosphate is present in an amount of 15 to 45 weight percent, based on the total weight of the composition.
19. The composition of claim 10 wherein the polyolefin comprises a homopolymer, a copolymer of ethylene and an alpha olefin having three to twelve carbons, a copolymer of ethylene and a functionalized alpha olefin having three to twelve carbons or a combination of two or more of the foregoing.
20. The composition of claim 10 wherein the organic phosphate is selected from the group consisting of tris(butyl phenyl) phosphate, resorcinol bis-diphenylphosphate, bis-phenol A bis-diphenylphosphate, triphenyl phosphate, tris(isopropyl phenyl) phosphate and mixtures of two or more of the foregoing; the phosphoric acid salt is melamine polyphosphate; and the metal hydroxide comprises magnesium hydroxide, aluminum hydroxide, cobalt hydroxide and combinations of two or more of the foregoing.
21. The composition of claim 20 wherein the metal hydroxide comprises magnesium hydroxide.
22. A coated wire comprising an electrically conductive core at least partially covered by the thermoplastic composition of claim 10 .
23. A flame retardant thermoplastic composition comprising:
a thermoplastic resin; and
a single flame retardant additive composition consisting of
a phosphoric acid salt selected from the group consisting of melamine phosphate, melamine pyrophosphate, melamine orthophosphate, diammonium phosphate, monoammonium phosphate, phosphoric acid amide, melamine polyphosphate, ammonium polyphosphate, polyphosphoric acid amide and combinations of two or more of the foregoing;
a metal hydroxide; and
an organic phosphate.
24. A flame retardant additive composition consisting of:
a phosphoric acid salt selected from the group consisting of melamine phosphate, melamine pyrophosphate, melamine orthophosphate, diammonium phosphate, monoammonium phosphate, phosphoric acid amide, melamine polyphosphate, ammonium polyphosphate, polyphosphoric acid amide and combinations of two or more of the foregoing;
a metal hydroxide; and
an organic phosphate.