IP Library Granted Patent US 8,361,946
Granted Patent B2
US 8,361,946 · App. 11/100,634 · Granted Jan 29, 2013

Detergent composition

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 8,361,946
App. No.
11/100,634
Granted
Jan 29, 2013
Kind
B2
Abstract

The invention relates to a method of preparing an aqueous detergent dispersion comprising mixing at least one silane compound, colloidal silica particles, and a detergent to form an aqueous detergent dispersion comprising silanized colloidal silica particles. The invention also relates to a dispersion obtainable by the method and to the use thereof.

Claims (20)

1. A method of preparing an aqueous detergent dispersion comprising mixing at least one silane compound and colloidal silica particles in an aqueous dispersion in a weight ratio of silane to silica of about 0.1 to about 1.5, optionally comprising an organic solvent miscible with water, wherein no organosiloxane or silicone are admixed for preparing a silicone coat on any silica particles or silane-modified silica particles to form an aqueous dispersion of silanized colloidal silica particles, adding a detergent comprising at least one anionic and/or non-ionic surfactant to said dispersion to form an aqueous detergent dispersion comprising silanized colloidal silica particles, wherein said detergent is added in an amount resulting in a detergent content from about 2 to about 80 wt % based on the detergent dispersion, wherein the total amount of organic solvent miscible with water, if present, is present in an amount of about 20 volume % or less based on the total dispersion volume.

2. A method according to claim 1 , wherein said at least one silane compound is an epoxy silane.

3. A method according to claim 1 , wherein said at least one silane compound is an epoxy silane with a glycidoxy group.

4. A method according to claim 1 , wherein said at least one silane compound is mixed with the silica particles in a weight ratio of silane to silica of about 0.1 to about 1.

5. An aqueous detergent dispersion obtained by mixing at least one silane compound and colloidal silica particles in an aqueous dispersion in a weight ratio of silane to silica of about 0.1 to about 1.5, wherein no organosiloxane or silicone are admixed for preparing a silicone coat on any silica particles or silane-modified silica particles, optionally comprising an organic solvent miscible with water in an amount from about 1 to about 20 volume % of the total dispersion volume, to form an aqueous dispersion of silanized colloidal silica particles, adding a detergent comprising at least one anionic and/or non-ionic surfactant to said dispersion to form an aqueous detergent dispersion comprising silanized colloidal silica particles, wherein the detergent content in said dispersion is from about 2 to about 80 wt %.

6. An aqueous detergent dispersion optionally comprising an organic solvent miscible with water in an amount from about 1 to about 20 volume % of the total dispersion volume comprising silanized colloidal silica particles and a detergent comprising at least one anionic and/or non-ionic surfactant having a content of from about 2 to about 80 wt % based on the weight of the dispersion wherein the weight ratio of silane to silica ranges from about 0.1 to about 1.5, and wherein no organosiloxane or silicone are comprised.

7. A dispersion according to claim 5 , wherein the silica content is from about 0.01 to about 20 wt %.

8. A dispersion according to claim 6 , wherein the silica content is from about 0.01 to about 20 wt %.

9. A dispersion according to claim 6 , wherein the dispersion is obtained by mixing at least one silane compound and colloidal silica particles in an aqueous dispersion.

10. A method according to claim 1 , wherein said detergent content is from about 2 to about 10 wt %.

11. A method according to claim 1 , wherein said detergent content is from about 30 to about 50 wt %.

12. A method according to claim 1 , wherein said detergent content is from about 50 to about 80 wt %.

13. A method according to claim 1 , wherein no organosiloxane or silicone is admixed in said aqueous dispersion.

14. A method according to claim 1 , wherein said colloidal silica particles have an average particle diameter ranging from about 2 to about 150 nm and a relative standard deviation of particle size distribution lower than about 60% by numbers.

15. A method according to claim 14 , wherein said average particle diameter ranges from about 3 to about 50 nm and a relative standard deviation of particle size distribution lower than about 30% by numbers.

16. A method according to claim 4 , wherein the weight ratio of silane to silica is from about 0.1 to about 0.5.

17. A method according to claim 4 , wherein said detergent dispersion remains stable for at least one month at about 55° C.

18. A method according to claim 1 , wherein the silica content is from about 0.01 to about 20 wt %.

19. A method according to claim 1 , wherein the aqueous detergent dispersion is prepared with the proviso that no organosiloxane or silicone is admixed in the aqueous dispersion for preparing a silicone coat on silica particles or silane-modified silica particles.

20. A method according to claim 1 , wherein the colloidal silica particles are added in the form of an aqueous silica sol having an S-value from about 60 to about 90.

Assignments (5)
CHANGE OF NAME Recorded Sep 18, 2019
From: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
To: NOURYON CHEMICALS INTERNATIONAL B.V.
Reel/Frame 050426/0671 →
SECURITY INTEREST Recorded Oct 1, 2018
From: STARFRUIT US MERGER SUB 1 LLC; STARFRUIT US MERGER SUB 2 LLC; AKZO NOBEL SURFACE CHEMISTRY LLC; AKZO NOBEL CHEMICALS B.V.; AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
To: WILMINGTON TRUST (LONDON) LIMITED, AS COLLATERAL AGENT
Reel/Frame 047231/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 13, 2017
From: AKZO NOBEL N.V.
To: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
Reel/Frame 044427/0759 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 1, 2005
From: GREENWOOD, PETER; LAGNEMO, HANS
To: AKZO NOBEL N.V.
Reel/Frame 016462/0776 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 30, 2005
From: GREENWOOD, PETER; LAGNEMO, HANS
To: AKZO NOBEL N.V.
Reel/Frame 016454/0627 →