Conductive roll and method for producing same
View Patent ↗A conductive roll having at least one conductive elastic layer on the outer periphery of a core bar, the conductive elastic layer being granted conductivity by carbon black, is provided. The conductive elastic layer is prepared by reacting at least a polyol consisting essentially of a polyether-based polyol with a diisocyanate with the use of a tetravalent organotin-based compound having a tin content of 18.7% or less by weight as a catalyst. A method for producing the conductive roll is also provided.
1. A conductive roll having at least one conductive elastic layer on an outer periphery of a core bar, the conductivity of the elastic layer being provided by carbon black,
wherein the conductive elastic layer is prepared by reacting, in a mold, three components consisting of a polyol, a diisocyanate and a catalyst wherein the polyol consists essentially of a polyether-based polyol having an average functional group number of 2.5 or more per molecule and is reacted with the diisocyanate having an average functional group number of more than 2 per molecule at an NCO/OH mol ratio of less than 1 in the presence of a catalytic amount of tetravalent organotin-based compound having a tin content of 18.7% or less by weight and wherein the organotin-based compound has sulfur atoms bound adjacent to tin atoms, wherein the organotin-based compound is selected from the group of dibutyltin bisisononyl-3-mercaptopropionate and dibutyltin bisisooctylthioglycollate, wherein the organotin-based compound is 0.001 to 0.05% by weight based on said polyol.
2. The conductive roll according to claim 1 , including a surface treatment layer on a surface of said conductive elastic layer, said surface treatment layer being formed by surface treatment with a surface treating solution containing at least an isocyanate component.
3. The conductive roll according to claim 2 , wherein said surface treating solution further contains at least one of carbon black and at least one polymer selected from the group consisting of an acrylic fluorine-based polymer and an acrylic silicone-based polymer.
4. The conductive roll according to claim 1 , wherein a relation between a resistance component Zr (Ω) and a capacitive reactance component Zc (Ω) calculated from impedance Z (Ω) when an alternating voltage of 0.2 V having a frequency of 1 Hz is applied to said conductive elastic layer satisfies the following equation:
25 ≧Zr/Zc≧ 5.
5. A method for producing a conductive roll having at least one conductive elastic layer on an outer periphery of a core bar, said conductive elastic layer being granted conductivity by carbon black, comprising:
reacting a polyol consisting essentially of a polyether-based polyol having an average functional group number of 2.5 or more per molecule with a diisocyanate having an average functional group number of more than 2 per molecule at an NCO/OH mol ratio of less than 1 in the presence of a catalytic amount of a tetravalent organotin-based compound having a tin content of 18.7% or less by weight to prepare said conductive elastic layer and wherein the organotin-based compound has sulfur atoms bound adjacent to tin atoms, wherein the organotin-based compound is selected from the group of dibutyltin bisisononyl-3-mercaptopropionate and dibutyltin bisisooctylthioglycollate, wherein the catalytic amount of said organotin-based compound is 0.001 to 0.05% by weight based on said polyol.
6. The method for producing a conductive roll according to claim 5 , further comprising a step of forming a surface treatment layer on a surface of said conductive elastic layer by surface treatment with a surface treating solution containing at least an isocyanate component.
7. The method for producing a conductive roll according to claim 6 , wherein said surface treating solution further contains at least one of carbon black and at least one polymer selected from the group consisting of an acrylic fluorine-based polymer and an acrylic silicone-based polymer.
8. The method for producing a conductive roll according to claim 5 , wherein a relation between a resistance component Zr (Ω) and a capacitive reactance component Zc (Ω) calculated from impedance Z (Ω) when an alternating voltage of 0.2 V having a frequency of 1 Hz is applied to said conductive elastic layer satisfies the following equation:
25 ≧Zr/Zc≧ 5.