Electron emission material, method of manufacturing the same, and electron emission element including the same
View Patent ↗The present invention provides an electron emission material that is excellent in electron emission characteristics, a method of manufacturing the same, as well as an electron emission element. The method is a method of manufacturing an electron emission material including a carbon material obtained by baking a polymer film. In the method, a polyamic acid solution is prepared in which at least one metallic compound selected from a metal oxide and a metal carbonate is dispersed; the polyamic acid solution thus prepared is formed into a film and then is imidized to form a polyimide film including the metallic compound; and then the polyimide film thus formed is baked to form the carbon material. The electron emission material is formed so that it includes a carbon material, a protrusion having a concavity in its surface is formed at the surface of the carbon material, and the protrusion includes a metallic element.
1. A method of manufacturing an electron emission material including a carbon material obtained by baking a polymer film, the method comprising:
preparing a polyamic acid solution in which at least one metallic compound selected from a metal oxide and a metal carbonate is dispersed;
forming the polyamic acid solution into a film and then imidizing it to form a polyimide film including the metallic compound; and
baking and thermally decomposing the polyimide film with letting nitrogen, oxygen and hydrogen leave from the polyimide film to form a carbon film,
wherein the polyimide film is baked at a temperature of 1200° C. to 3000° C.
2. The method of manufacturing an electron emission material according to claim 1 , wherein the metallic compound is a compound of at least one element selected from an alkali metal element and an alkaline earth metal element.
3. The method of manufacturing an electron emission material according to claim 2 , wherein the metallic compound is a compound of at least one element selected from the group consisting of Ca, Sr, Ba, Li, Na, K, Rb, and Cs.
4. The method of manufacturing an electron emission material according to claim 1 , wherein the metallic compound is particulate.
5. The method of manufacturing an electron emission material according to claim 4 , wherein the metallic compound has a mean particle size in a range of 10 nm to 100 μm.