Stimulable cerium activated lutetium borate phosphor
View Patent ↗A cerium activated lutetium borate phosphor of the following formula (I): (Lu x ,Ln y )BO 3 :a Ce, b A (I) in which Ln is at least one rare earth element selected from the group consisting of Y, La and Gd; A is at least one element selected from the group consisting of Pr, Nd, Pm, Sm, Eu, Tb, Dy, Ho, Er, Tm, Yb and Zr; and x, y, a and b are numbers satisfying the conditions of 0.5≦ x< 1, 0≦ y< 0.5, 0< a≦ 0.2, 0≦ b≦ 0.2 and x+y+a+b= 1.0 , gives a stimulated emission off when it is excited with an electromagnetic wave after exposing to a radiation such as X-rays.
1. A radiation image storage panel having a phosphor layer which comprises a stimulable cerium activated lutetium borate phosphor represented by the following formula (I):
(Lu x ,Ln y )BO 3 :a Ce, b A (I)
in which Ln is at least one rare earth element selected from the group consisting of Y, La and Gd; A is at least one element selected from the group consisting of Pr, Nd, Pm, Sm, Eu, Tb, Dy, Ho, Er, Tm, Yb and Zr; and x, y, a and b are numbers satisfying the conditions of 0.5≦x<1, 0≦y<0.5, 0<a≦0.2, 0≦b≦0.2 and x+y+a+b=1.0.
2. The radiation image storage panel of claim 1 , in which A of the formula (I) is Sm or Zr.
3. The radiation image storage panel of claim 1 , in which b of the formula (I) is 0.
4. The radiation image storage panel of claim 1 , in which y of the formula (I) is 0.
5. The radiation image storage panel of claim 1 , which comprises a support, the phosphor layer and a protective layer in order.
6. A method for producing a stimulated emission which comprises the steps of:
applying a radiation to a stimulable cerium activated lutetium borate phosphor of the following formula (I):
(Lu x ,Ln y )BO 3 :a Ce, b A (I)
in which Ln is at least one rare earth element selected from the group consisting of Y, La and Gd; A is at least one element selected from the group consisting of Pr, Nd, Pm, Sm, Eu, Tb, Dy, Ho, Er, Tm, Yb and Zr; and x, y, a and b are numbers satisfying the conditions of 0.5≦x<1, 0≦y<0.5, 0<a≦0.2, 0≦b≦0.2 and x+y+a+b=1.0, whereby storing an energy of the radiation in the phosphor and
stimulating the phosphor in which the energy of the radiation is stored with a stimulating light, whereby giving a stimulated emission off.
7. The method of claim 6 , in which A of the formula (I) is Sm or Zr.
8. The method of claim 6 , in which b of the formula (I) is 0.
9. The method of claim 6 , in which y of the formula (I) is 0.
10. A radiation image recording and reproducing method comprising the steps of:
exposing the radiation image storage panel of claim 1 to a radiation having passed through an object or having radiated from an object, whereby a spatial energy distribution of the radiation is recorded as a latent image in the phosphor layer of the storage panel;
irradiating the storage panel with a stimulating light to emit a stimulated light from the latent image in the phosphor layer;
photoelectrically detecting and converting the stimulated light to image signals; and
forming a radiation image from the image signals.