Nano-particle preparation and applications
View Patent ↗A nano-particle composition including a poly(alkenylbenzene) core and a poly (conjugated diene) or a poly(alkylene) surface layer is provided. The nano-particles have a mean average diameter less than about 100 nm. The nano-particles can be modified via, for example, hydrogenation or functionalization. The nano-particles can advantageously be incorporated into rubbers, elastomers, and thermoplastics.
1. A nanoparticle composition comprising:
a. a poly(alkenylbenzene) core, wherein the polyalkenylbenzene core is one or more monomer units selected from the group consisting of: styrene, α-methylstyrene, 1-vinyl naphthalene, 2-vinyl naphthalene, 1-α-methyl vinyl naphthalene, 2-α-methyl vinyl naphthalene, vinyl toluene, methoxystyrene, t-butoxystyrene; alkyl, cycloalkyl, aryl, alkaryl, and aralkyl derivatives of the foregoing in which the total number of carbon atoms in the combined hydrocarbon is not greater than 18, and any di- or tri-vinyl substituted aromatic hydrocarbons; and
b. a surface layer comprising poly(conjugated diene) wherein the surface layer is one or more monomer units selected from the group consisting of C 4 to C 8 conjugated diene monomers;
with the proviso that the core and shell are not made by emulsion polymerization.
2. The nanoparticle composition of claim 1 , wherein the nanoparticle composition is formed by the following steps:
polymerizing alkenylbenzene monomer and conjugated diene monomer in a hydrocarbon solvent to form a diblock polymer;
forming a polymerization mixture including micelles of said diblock polymer; and
adding at least one crosslinking agent to the polymerization mixture to form nanoparticle composition from said micelles.
3. The nanoparticle composition of claim 2 , wherein the polymerizing step is performed in the presence of a lithium initiator.
4. The nanoparticle composition of claim 2 , wherein subsequent to the polymerizing step further hydrocarbon solvent is added to the polymerization mixture.
5. The nanoparticle composition of claim 2 wherein said crosslinking agent is a multifunctional organic compound.
6. The nanoparticle composition of claim 2 wherein said conjugated diene monomer is chosen from one or more of 1,3-butadiene, isoprene, and 1,3-pentadiene.
7. The nanoparticle composition of claim 2 wherein said nano-particles have a mean average diameter of less than 100 nm.
8. The process of claim 2 wherein said hydrocarbon solvent is selected from one or more of pentane, hexane, heptane, octane, nonane, decane, cyclohexane, methyl cyclopentane, cyclooctane, cyclopentane, cycloheptane, cyclononane, and cyclodecane.
9. The process of claim 2 wherein the polymerizing step is performed at between about −40 and 200° C.
10. The nanoparticle composition of claim 1 , wherein the C 4 to C 8 conjugated diene monomers are selected from the group comprising 1,3-butadiene, isoprene, and 1,3-pentadiene.
11. The nanoparticle of claim 1 wherein the nanoparticle is made by living anionic polymerization.
12. A nanoparticle composition comprising:
a. a cross-linked core comprising poly(alkenylbenzene), and
b. a surface layer comprising a poly(alkylene) or a mixture of poly(conjugated diene) and poly(alkylene), the surface layer having a brush-like structure.
13. The nanoparticle of claim 12 wherein the core further comprises a mono-block polymer.