Stainless steel for high-pressure hydrogen gas
View Patent ↗A high-strength stainless steel, having good mechanical properties and corrosion resistance in a high-pressure hydrogen gas environment, is used as a container or other device for high-pressure hydrogen gas, and consists of, by mass %, C: not more than 0.04%, Si: not more than 1.0%, Mn: 7 to 30%, Cr: 15 to 22%, Ni: 5 to 20%, V: 0.001 to 1.0%, N: 0.20 to 0.50% and Al: not more than 0.10%, and the balance Fe and impurities. Among the impurities, P is not more than 0.030%, S is not more than 0.005%, and Ti, Zr and Hf are not more than 0.01% respectively, and the contents of Cr, Mn and N satisfy the relationship, 2.5Cr+3.4Mn≦300N. The weld metal of the welded joint of the container or other device made of the said stainless steel satisfies the relationship, −11≦Nieq−1.1×Creq≦−8.
1. A stainless steel for high-pressure hydrogen gas characterized in that:
(a) the steel consists of, by mass %, C: not more than 0.04%, Si: not more than 1.0%, Mn: 7 to 30%, Cr: 15 to 22%, Ni: 5 to 20%, V: 0.001 to 0.57%, N: 0.20 to 0.4510% and Al: not more than 0.10%, and optionally at least one element selected from at least one of the first, second and third groups of elements specified below, and the balance Fe and impurities,
(b) among the impurities, P is not more than 0.030%, S is not more than 0.005%, and Ti, Zr and Hf are not more than 0.01% respectively, and
(c) the contents of Cr, Mn and N satisfy the following relationship [1]:
2.5Cr+3.4Mn≦300N [1]
wherein the symbols of the elements represent the contents, % by mass, of the respective elements;
wherein the first group of elements is;
Mo: 0.3 to 3.0%, W: 0.3 to 6.0%, Nb: 0.001 to 0.20% and Ta: 0.001 to 0.40%;
wherein the second group of elements is;
B: 0.0001 to 0.020%, Cu: 0.3 to 5.0%, and Co: 0.3 to 10.00/a; and
wherein the third group of elements is;
Mg: 0.0001 to 0.0050%, Ca: 0.0001 to 0.0050%, La: 0.0001 to 0.200%, Ce: 0.0001 to 0.200%, Sm: 0.0001 to 0.40%, Pr: 0.0001 to 0.40%, and Nd: 0.0001 to 0.50%, and
d) the steel has a tensile strength of not lower than 863 MPa and a yield strength not lower than 534 MPa.
2. A high-strength stainless steel for high-pressure hydrogen gas, according to claim 1 , characterized in that the mean austenite grain size is not greater than 20 μm.
3. A high-strength stainless steel for high-pressure hydrogen gas, according to claim 1 , characterized in that fine nitride precipitates of not greater than 0.1 μm are dispersed in an amount of not less than 0.005% by volume.
4. A high-strength stainless steel for high-pressure hydrogen gas, according to claim 1 , characterized in that fine nitride precipitates of not greater than 0.1 μm are dispersed in an amount of not less than 0.005% by volume, and the fine nitride precipitates are at least partly face-centered cubic in crystal structure.
5. A high-strength stainless steel for high-pressure hydrogen gas, according to claim 1 , characterized in that fine nitride precipitates of not greater than 0.1 μm are dispersed in an amount of not less than 0.0050% by volume, the fine nitride precipitates contain not less than 10% by mass of V within them, and the fine nitride precipitates are at least partly face-centered cubic in crystal structure.
6. A high-strength stainless steel for high-pressure hydrogen gas, according to claim 1 , characterized in that the mean austenite grain size is not greater than 20 μm, fine nitride precipitates of not greater than 0.1 μm are dispersed in an amount of not less than 0.005% by volume.
7. A high-strength stainless steel for high-pressure hydrogen gas, according to claim 1 , characterized in that the mean austenite grain size is not greater than 20 μm, fine nitride precipitates of not greater than 0.1 μm are dispersed in an amount of not less than 0.005% by volume, and the fine nitride precipitates are at least partly face-centered cubic in crystal structure.
8. A high-strength stainless steel for high-pressure hydrogen gas, according to claim 1 , characterized in that the mean austenite grain size is not greater than 20 μm, fine nitride precipitates of not greater than 0.1 μm are dispersed in an amount of not less than 0.005% by volume, the fine nitride precipitates contain not less than 100% by mass of V within them, and the fine nitride precipitates are at least partly face-centered cubic in crystal structure.
9. A high-strength stainless steel according to claim 1 wherein the steel contains at least one element selected from the first group of elements.
10. A high-strength stainless steel according to claim 1 wherein the steel contains at least one element selected from the second group of elements.
11. A high-strength stainless steel according to claim 1 wherein the steel contains at least one element selected from the third group of elements.
12. A high-strength stainless steel according to claim 9 wherein the steel contains at least one element selected from the second group of elements.
13. A high-strength stainless steel according to claim 12 wherein the steel contains at least one element selected from the third group of elements.
14. A high-strength stainless steel according to claim 9 wherein the steel contains at least one element selected from the third group of elements.
15. A high-strength stainless steel according to claim 10 wherein the steel contains at least one element selected from the third group of elements.