In-reactor produced polypropylene blends
View Patent ↗Polypropylene resin compositions are provided that are useful in the production of thermoformed articles and biaxially oriented polypropylene films (BOPPs), tapes and fibers. The resins of the present invention are blends of high crystalline (low solubles) polypropylene homopolymer and an ethylene/propylene random copolymer (RCP). These blends can be used to replace standard high solubles BOPP grade polypropylene homopolymers. In addition, the use of high crystalline polypropylene homopolymers in the blends imparts improved stiffness to the finished films while maintaining good processability of the blends. Such polypropylene compositions are effectively produced by in-reactor blending of a high crystalline propylene homopolymer and a propylene/ethylene random copolymer.
1. A process for producing a polymer blend, said process comprising:
polymerizing propylene in the presence of a Ziegler Natta catalyst in a first stage of a two stage reactor train to produce a homopolymer having a xylene solubles content of less than 3%;
transferring the homopolymer to a second stage of the two stage reactor train; and
polymerizing propylene and ethylene in said second stage in the presence of the homopolymer to produce a propylene/ethylene random copolymer having an ethylene content of from about 0.5% to about 7%, to produce a blend of the homopolymer and random copolymer;
wherein the blend comprises from about 70 to about 95% by weight of the homopolymer and from about 5 to about 30% by weight of the random copolymer.
2. The process according to claim 1 , wherein:
the homopolymer has a crystalline content of at least 55%.
3. The process according to claim 1 , wherein:
the blend comprises from about 70 to about 90% of the homopolymer and from about 10 to about 30% of the random copolymer.
4. The process according to claim 1 , wherein:
the first stage reactor is a liquid phase reactor, and the second stage reactor is a gas phase reactor.
5. The process according to claim 1 , wherein:
the first stage reactor and the second stage reactor are both gas phase reactors.
6. A process for producing a polymer blend, said process comprising:
polymerizing propylene in the presence of a Ziegler-Natta catalyst and hydrogen in a first stage including at least one liquid phase polymerization reactor to produce a homopolymer having a crystalline content of at least 55% and a xylene solubles content of less than 3%;
transferring the homopolymer to a second stage including at least one gas phase reactor, wherein the homopolymer still contains active sites; and
polymerizing propylene and ethylene in said second stage in the presence of hydrogen and said homopolymer, to produce a propylene/ethylene random copolymer having an ethylene content of from about 0.5 to about 7%, to produce a blend of the homopolymer and random copolymer;
wherein the blend comprises from about 70 to about 95% by weight of the homopolymer and from about 5 to about 30% by weight of the random copolymer.
7. The process according to claim 6 , wherein:
the blend comprises from about 70 to about 90% of the homopolymer and from about 10 to about 30% of the random copolymer.
8. The process of claim 1 , wherein said polymerizing propylene in the presence of a Ziegler Natta catalyst in a first stage of a two stage reactor train takes place while maintaining 700 ppm hydrogen in said first stage.
9. The process of claim 6 , wherein said hydrogen is maintained at 700 ppm.
10. The process of claim 8 , wherein said propylene is fed into said first stage at 80 kg/h.
11. The process of claim 9 , wherein said propylene is fed into said first stage at 80 kg/h.