Diamond-silicon carbide composite
View Patent ↗Fully dense, diamond-silicon carbide composites are prepared from ball-milled microcrystalline diamond/amorphous silicon powder mixture. The ball-milled powder is sintered (P=5–8 GPa, T=1400K–2300K) to form composites having high fracture toughness. A composite made at 5 GPa/1673K had a measured fracture toughness of 12 MPa·m 1/2 . By contrast, liquid infiltration of silicon into diamond powder at 5 GPa/1673K produces a composite with higher hardness but lower fracture toughness. X-ray diffraction patterns and Raman spectra indicate that amorphous silicon is partially transformed into nanocrystalline silicon at 5 GPa/873K, and nanocrystalline silicon carbide forms at higher temperatures.
1. A fully dense diamond-silicon carbide composite made by the method comprising ball-milling a mixture of microcrystalline diamond powder and crystalline silicon to form a ball-milled powder mixture of microcrystalline diamond and amorphous silicon, then sintering the ball-milled powder mixture at a pressure of about 5 GPa to about 8 GPa and a temperature from about 1400K to about 2300K to form a fully dense diamond-silicon carbide composite comprising microcrystalline diamond and nanocrystalline silicon carbide and having a fracture toughness of at least 10 MPa·m 1/2 with minimal graphitization.
2. The composite of claim 1 having a fracture toughness of 12 MPa·m 1/2 .
3. The composite of claim 1 , wherein the ball-milled powder is sintered at a pressure of about 5 GPa and a temperature of about 1423K to about 1523K.
4. The composite of claim 1 , wherein the ball-milled powder is sintered at a pressure of about 5 GPa and a temperature of about 1623K to about 1723K.
5. The composite of claim 1 , wherein the ball-milled powder is sintered at a pressure of about 8 GPa and a temperature of about 2223K to about 2300K.