Branched polyamides comprising unsaturated ends
View Patent ↗The present invention relates to branched polyamides comprising unsaturated ends comprising: at least one unit originating from a multifunctional monomer (A) having more than two functional groups, at least sequences resulting from the condensation, in the presence of at least one unsaturated monoacid, either of at least two different lactams, or of at least one lactam, at least one dicarboxylic acid and at least one diamine, or of a lactam or of an α,ω-aminocarboxylic acid, or of a diamine and of a diacid. The invention also relates to thermofusible adhesives comprising these branched polyamides comprising unsaturated ends, and to the use of these branched polyamides comprising unsaturated ends in sheathing electrical cables.
1. A crosslinkable branched polyamide comprising unsaturated ends wherein the polyamide results from the condensation of 11-aminoundecanoic acid, caprolactam, lauryllactam, diethylenetriamine, undecylenic acid and hexamethylenediamine, the proportion of diethylenetriamine being from 0.05 to 2% by weight with respect to the combination of 11-aminoundecanoic acid, caprolactam, lauryllactam, diethylenetriamine, undecylenic acid and hexamethylenediamine, and wherein said hexamethylenediamine is present in excess so all undecylenic acid is attached to the polymer, wherein said polyamide has more than 2 unsaturated ends, and wherein said polyamide is both branched and crosslinkable and is suitable for use as a thermofusible adhesive.
2. A process for the manufacture of a polyamide according to claim 1 , comprising condensing, in the presence of an unsaturated monoacid, wherein the unsaturated monoacid is undecylenic acid as a chain-limiting agent and allowing the direct incorporation of said unsaturated ends,
11-aminoundecanoic acid, caprolactam, lauryllactam, and hexamethylenediamine as monomers;
wherein diethylenetriamine is added either during the condensation of the monomers or subsequent to the condensation of the monomers.
3. A thermofusible adhesive comprising the crosslinkable branched polyamide comprising unsaturated ends according to claim 1 .
4. The thermofusible adhesive of claim 3 comprising the sheathing of an electrical cable.
5. A crosslinkable branched polyamide comprising unsaturated ends wherein the polyamide results from the condensation of caprolactam, adipic acid, hexamethylenediamine, lauryllactam, diethylenetriamine and undecylenic acid, the proportion of diethylenetriamine being from 0.05 to 2% by weight with respect to the combination of caprolactam, adipic acid, hexamethylenediamine, lauryllactam, diethylenetriamine and undecylenic acid, and wherein said hexamethylenediamine is present in excess so all undecylenic acid is attached to the polymer, wherein said polyamide has more than 2 unsaturated ends, and wherein said polyamide is both branched and crosslinkable and is suitable for use as a thermofusible adhesive.
6. A process for the manufacture of a polyamide according to claim 5 , comprising condensing, in the presence of an unsaturated monoacid, wherein the unsaturated monoacid is undecylenic acid as a chain-limiting agent and allowing the direct incorporation of said unsaturated ends, caprolactam, adipic acid, hexamethylenediamine, and lauryllactam as monomers, wherein diethylenetriamine is added either during the condensation of the monomers or subsequent to the condensation.
7. A thermofusible adhesive comprising the crosslinkable branched polyamide comprising unsaturated ends according to claim 5 .
8. The thermofusible adhesive of claim 7 comprising the sheathing of an electrical cable.