Synthetic material having selective expansion characteristics

1 . A synthetic material comprising:

a mass of expandable material having at least one surface; and

a layer of oriented material contacting the mass of expandable material, wherein, upon expansion of the expandable material, the layer of oriented material contracts in at least one direction and directs expansion of the expandable material in one or more directions substantially perpendicular to the at least one direction.

2 . A synthetic material as in claim 1 wherein the layer of oriented material is a stretched portion of the mass of expandable material.

3 . A synthetic material as in claim 2 wherein the entirety of the mass of expandable material is stretched to form the layer of oriented material.

4 . A synthetic material as in claim 1 wherein the layer of oriented material is a separate film that is disposed upon a surface of the mass of expandable material.

5 . A synthetic material as in claim 1 wherein the layer of oriented material contracts due to crystalline orientation of the region.

6 . A synthetic material as in claim 1 wherein the mass of expandable material expands upon exposure to a temperature typically experienced in an automotive e-coat, paint or primer oven.

7 . A synthetic material as in claim 6 wherein the mass of expandable material is a thermosettable material.

8 . A synthetic material as in claim 7 wherein the mass of expandable material includes an epoxy resin, an acrylate or an acetate.

9 . A synthetic material as in claim 1 wherein the mass of expandable material includes at least one elastomer.

10 . A synthetic material as in claim 1 wherein the mass of expandable material includes a blowing agent or a curing agent that becomes reactive at a temperature typically experienced in an automotive e-coat or paint oven.

11 . A synthetic material comprising:

a mass of expandable material having at least one surface; and

a layer disposed upon the at least one surface, the layer being a film wherein;

i) the film includes a peripheral region and a central region;

ii) upon expansion of the expandable material, the film contracts in directions parallel to the at least one surface such that the peripheral region moves toward the central region, which causes mass of expandable material to expand further away from the layer.

12 . A synthetic material as in claim 11 wherein the surface of the mass of expandable material is tacky for assisting in adhering the film to the surface.

13 . A synthetic material as in claim 11 wherein the film is of a size that leaves an outer region of the surface of the mass of expandable material exposed

14 . A synthetic material as in claim 11 wherein the film is substantially continuous upon the surface of the mass of expandable material.

15 . A synthetic material as in claim 11 wherein the film is formed of a crystalline polymeric material.

16 . A synthetic material as in claim 11 wherein the film is crystallized to have a uniaxial or biaxial orientation.

17 . A synthetic material as in claim 11 wherein the film has a largest thickness that is less than about 0.2 mm.

18 . A synthetic material as in claim 11 wherein the film has a smallest thickness that is greater than about 0.01 mm.

19 . A synthetic material as in claim 1 wherein:

i. the film is formed of an oriented stretched crystalline material;

ii. the mass of expandable material expands upon exposure to a temperature typically experienced in an automotive e-coat, paint or primer oven;

iii. the mass of expandable material is a thermosettable material;

iv. the mass of expandable material includes an epoxy resin, an acrylate or an acetate; and

v. the mass of expandable material includes at least one elastomer.

20 . A method of providing sealing, reinforcement or baffling to a structure of an article of manufacture, the method comprising:

providing a synthetic material wherein the synthetic material includes:

i) a mass of expandable material having at least one surface; and

ii) a layer disposed upon the at least one surface, the layer being a film having a peripheral region and a central region substantially entirely surrounded by the peripheral region;

placing a synthetic material within a cavity defined by at least one wall of the structure such that the film is located substantially entirely between the at least one wall and the mass of expandable material;

heating the synthetic material causing the expandable material to expand and simultaneously causing the film to contract in directions parallel to the at least one surface wherein:

i) the film contracts such that the peripheral region moves toward the central region causing the expandable material to expand further away from the film.