Negative electrode for non-aqueous electrolyte secondary battery and non-aqueous electrolyte secondary battery comprising the same
View Patent ↗A negative electrode containing an alloying material and a graphite material for providing a non-aqueous electrolyte secondary battery with a high capacity and excellent cycle characteristics. The negative electrode includes graphite and an alloying material capable of electrochemically absorbing and desorbing Li. The alloying material includes an A phase composed mainly of Si and a B phase including an intermetallic compound of a transition metal element and Si. The A phase and/or the B phase include a microcrystalline or amorphous region. The weight percentage of the A phase relative to the total weight of the A phase and the B phase is greater than 40% and not greater than 95%. The weight percentage of the graphite relative to the total weight of the alloying material and the graphite is not less than 50% and not greater than 95%.
1. A negative electrode for a non-aqueous electrolyte secondary battery, comprising graphite and an alloying material capable of electrochemically absorbing and desorbing Li,
said alloying material comprising an A phase composed mainly of Si and a B phase comprising an intermetallic compound of at least one transition metal element and Si,
at least one of said A phase and said B phase comprising a microcrystalline or amorphous region,
the weight percentage of said A phase relative to the total weight of said A phase and said B phase being greater than 40% and not greater than 95%,
the weight percentage of said graphite relative to the total weight of said alloy material and said graphite being not less than 65% and not greater than 85%, wherein:
said alloying material exists in gaps between particles of said graphite,
said alloying material has a maximum particle size of 10 μm or less, and
the ratio of the mean particle size of said alloying material to the mean particle size of said graphite is in the range of 0.15 to 0.90.
2. The negative electrode for a non-aqueous electrolyte secondary battery in accordance with claim 1 , further comprising an auxiliary conductive agent, said auxiliary conductive agent having a specific surface area of 10 m 2 /g or more.
3. The negative electrode for a non-aqueous electrolyte secondary battery in accordance with claim 2 , wherein the weight percentage of said auxiliary conductive agent relative to the total weight of said alloying material, said graphite and said auxiliary conductive agent is 10% or less.
4. The negative electrode for a non-aqueous electrolyte secondary battery in accordance with claim 1 , wherein both said A phase and said B phase comprises a microcrystalline or amorphous region.
5. A non-aqueous electrolyte secondary battery comprising a positive electrode capable of electrochemically absorbing and desorbing Li, a negative electrode and a non-aqueous electrolyte,
said negative electrode comprising graphite and an alloying material capable of electrochemically absorbing and desorbing Li,
said alloying material comprising an A phase composed mainly of Si and a B phase comprising an intermetallic compound of at least one transition metal element and Si,
at least one of said A phase and said B phase comprising a microcrystalline or amorphous region,
the weight percentage of said A phase relative to the total weight of said A phase and said B phase being greater than 40% and not greater than 95%,
the weight percentage of said graphite relative to the total weight of said alloying material and said graphite being not less than 65% and not greater than 85%, wherein:
said alloying material exists in gaps between particles of said graphite,
said alloying material has a maximum particle size of 10 μm or less, and
the ratio of the mean particle size of said alloying material to the mean particle size of said graphite is in the range of 0.15 to 0.90.