Aqueous silica-containing composition
View Patent ↗The present invention refers to a process for the production of paper from a suspension containing cellulosic fibers, and optionally fillers, comprising adding to the suspension at least one cationic organic polymer and an aqueous silica-containing composition comprising an anionic naphthalene sulphonate formaldehyde condensate and anionic silica-based particles, the composition having a weight ratio of naphthalene sulphonate formaldehyde condensate to silica-based particles within the range of from 0.2:1 to 99:1, and containing naphthalene sulphonate formaldehyde condensate and silica-based particles in an amount of at least 0.01% by weight, based on the total weight of the aqueous silica-containing composition, and with the proviso that the composition contains substantially no cellulose-reactive sizing agent. The invention also encompasses an aqueous silica-containing composition and a method for preparation of an aqueous silica-containing compound.
1. An aqueous silica-containing composition comprising an anionic naphthalene sulphonate formaldehyde condensate and aggregated or microgel formed anionic silica-based particles, wherein the composition has a weight ratio of naphthalene sulphonate formaldehyde condensate to total amount of silica-based particles within the range of from 0.2:1 to 99:1, and wherein the amount of naphthalene sulphonate formaldehyde condensate and total amount of silica-based particles is at least 0.01% by weight, based on the total weight of the aqueous silica-containing composition, and with the provisos that the composition contains substantially no cellulose-reactive sizing agent and the composition is not a cellulosic papermaking stock, wherein the anionic naphthalene sulphonate formaldehyde condensate has a conductivity of less than 15 mS/cm measured at an anionic naphthalene sulphonate formaldehyde condensate content of 10% by weight.
2. The aqueous silica-containing composition according to claim 1 wherein the aqueous silica-containing composition has a weight ratio of naphthalene sulphonate formaldehyde condensate to total amount of silica-based particles within the range of from 0.2:1 to 90:1.
3. The aqueous silica-containing composition according to claim 2 wherein the silica-based particles have a specific surface area within the range of from 300 to 1300 m 2/ g.
4. The aqueous silica-containing composition according to claim 2 wherein the weight ratio of naphthalene sulphonate formaldehyde condensate to total amount of silica-based particles within the range of from 0.25:1 to 85:1.
5. The aqueous silica-containing composition according to claim 1 wherein the silica-based particles have a specific surface area within the range of from 300 to 1300 m 2/ g.
6. The aqueous silica-containing composition according to claim 1 wherein the composition is an additive for a cellulosic papermaking stock.
7. The aqueous silica-containing composition according to claim 1 wherein the composition is a flocculation agent for treating water.
8. A method for the preparation of an aqueous silica-containing composition which comprises mixing an aqueous anionic naphthalene sulphonate formaldehyde condensate solution having a conductivity less than 15 mS/cm with an aqueous alkali stabilised sol containing silica-based particles wherein the prepared aqueous silica-containing composition contains naphthalene sulphonate formaldehyde condensate and total amount of silica-based particles in an amount of at least 0.01% by, weight, wherein the conductivity is measured at an anionic naphthalene sulphonate formaldehyde condensate content of 10% by weight.
9. The method according to claim 8 wherein the aqueous silica-containing composition has a weight ratio of naphthalene sulphonate formaldehyde condensate to total amount of silica-based particles within the range of from 0.2:1 to 90:1.
10. The method according to claim 9 wherein the weight ratio of naphthalene sulphonate formaldehyde condensate to total amount of silica-based particles within the range of from 0.25:1 to 85:1.
11. The method according to claim 8 wherein the silica-based particles have a specific surface area within the range of from 300 to 1300 m 2/ g.
12. The method according to claim 8 wherein the silica-based particles have an S-value within the range of from 5 to 50% prior to mixing with the anionic of naphthalene sulphonate formaldehyde condensate.
13. The method according to claim 8 wherein the silica-based particles have an S-value within the range of from 8 to 45% prior to mixing with the anionic of naphthalene sulphonate formaldehyde condensate.
14. The method according to claim 8 wherein it further comprises desalinating the aqueous anionic naphthalene sulphonate formaldehyde condensate solution prior to mixing it with the aqueous alkali stabilised sol containing silica-based particles.
15. An aqueous silica-containing composition comprising an anionic naphthalene sulphonate formaldehyde condensate and aggregated or microgel formed anionic silica-based particles, wherein the composition has a weight ratio of naphthalene sulphonate formaldehyde condensate to total amount of silica-based particles within the range of from 0.2:1 to 99:1, and wherein the amount of naphthalene sulphonate formaldehyde condensate and total amount of silica-based particles is at least 0.5 % by weight, based on the total weight of the aqueous silica-containing composition, and with the proviso that the composition contains substantially no cellulose-reactive sizing agent, wherein the anionic naphthalene sulphonate formaldehyde condensate has a conductivity of less than 15 mS/cm measured at an anionic naphthalene sulphonate formaldehyde condensate content of 10% by weight.
16. The aqueous silica-containing composition according to claim 15 wherein the amount of naphthalene sulphonate formaldehyde condensate and total amount of silica-based particles is in the range of 1 to 45% by weight, based on the total weight of the aqueous silica-containing composition.
17. The aqueous silica-containing composition according to claim 16 wherein the amount of naphthalene sulphonate formaldehyde condensate and total amount of silica-based particles is in the range of 2 to 35% by weight, based on the total weight of the aqueous silica-containing composition.
18. The aqueous silica-containing composition according to claim 17 wherein the amount of naphthalene sulphonate formaldehyde condensate and total amount of silica-based particles is in the range of 5 to 30% by weight, based on the total weight of the aqueous silica-containing composition.