Demulsifiers for mixtures of middle distillates with fuel oils of vegetable or animal origin and water
View Patent ↗The present invention relates to the preparation of Ω-(dimethylisopropenylbenzylurethane) polyalkylene glycols with α-alkoxy or α-dihydroxy groups and to the use thereof as hydrolysis-stable macromonomers for the dispersion and crosslinking of polymers in which, A is C 2 -C 4 -alkylene, m is an integer from 5 to 900, and R is C 1 -C 20 -alkyl, C 6 -C 18 -aryl or a radical according to formula 2a, 2b, 2c, 3a, 3b or 3c which is bonded to the terminal oxygen atom of the alkoxy group (A-O) in formula 1 via the valence denoted by *, and in which A is not exclusively C 3 - or C 4 -alkylene.
1. A fuel oil comprising a major proportion of a mixture of
A) a middle distillate fuel oil and
B) a biofuel oil, and a minor proportion
C) of an oil-soluble oligo- or polyethyleneimine which has been alkoxylated with from 1 to 100 C 2 -C 4 -alkylene oxide groups or a mixture of said alkylene oxide groups per free NH group.
2. The fuel oil as claimed in claim 1 , wherein a mixing ratio A):B) is from 99:1 to 1:99.
3. The fuel oil of claim 1 , wherein the alkoxylated oligo- or polyethyleneimine C) has a molecular weight of between 55 000 and 1 000 000 g/mol.
4. The fuel oil of claim 1 , wherein the alkoxylated oligo- or polyethyleneimine C) has a water number of from 6 to 25 ml.
5. The fuel oil of claim 1 , wherein the alkoxylated oligo- or polyethyleneimine C) has a degree of alkoxylation of from 2 to 80 alkylene oxide units per free NH group.
6. The fuel oil of claim 1 , wherein the alkoxylated oligo- or polyethyleneimine C) corresponds to the formulae 1and 2
where l, m and n are each independently from 0 to 100 and (x+y) is equal to from 1 to 100.
7. The fuel oil of claim 1 , wherein C) is from 0.001 to 5% by weight.
8. The fuel oil of claim 1 , wherein the mixture further comprises at least one alkylphenol-formaldehyde resin of the formula
where R A is C 4 -C 30 -alky or -alkenyl, R B is OH or O-(A-O) x -H wheren A=C 2 -C 4 -alkylene and x=from 1 to 50, and n is from 2 to 50.
9. The fuel oil of claim 1 , which further comprises at least one copolymer which comprises from 60 to 90% by weight of ethylene, and a comonomer selected from the group consisting of from 10 to 40% by weight of vinyl acetate, from 1 to 40% by weight of a long-chain vinylester, from 0.5 to 20% by weight of an olefin, and mixtures thereof.
10. The fuel oil of claim 1 , which further comprises at least one amine salt, imide or amide of a primary and/or secondary fatty amine having from 8 to 36 carbon atoms.
11. The fuel oil of claim 1 , which further comprises at least one copolymer which is derived from an amide, an imide, an ester and mixtures thereof of an acid selected from the group consisting of maleic acid, fumaric acid, itaconic acid, and mixtures thereof.
12. The fuel oil of claim 1 , which further comprises a comb polymer of the formula
where
A is R′, COOR′, OCOR′, R″-COOR′ or OR′;
D is H, CH 3 , A or R;
E is H or A;
G is H, R″, R″-COOR′, an aryl radical or a heterocyclic radical;
M is H, COOR″, OCOR″, OR″ or COOH;
N is H, R″, COOR″, OCOR″, COOH or an aryl radical;
R′ is a hydrocarbon chain having 8-150 carbon atoms;
R″ is a hydrocarbon chain having from 1to 10 carbon atoms;
m is between 0.4 and 1.0; and
n is between 0 and 0.6.
13. A method for the demulsification of mixtures of middle distillate fuel oils, biofuel oils, and water, said method comprising adding to said mixture an oil-soluble oligo- or polyethyleneimine which have been alkoxylated with from 1 to 100 C 2 -C 4 -alkylene oxide groups or a mixture of said alkylene oxide groups per free NH group.