IP Library Granted Patent US 7,301,057
Granted Patent B2
US 7,301,057 · App. 11/137,761 · Granted Nov 27, 2007

Process for preparing TCD-alcohol DM

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Quick Facts
Patent No.
US 7,301,057
App. No.
11/137,761
Granted
Nov 27, 2007
Kind
B2
Abstract

The present invention relates to a process for preparing 3(4),8(9)-dihydroxymethyltricyclo[5.2.10 2.6 ]decane by hydrogenating the hyd roformylation products of d icyclopentad lene. The process comprises carrying out the hydrogenation in the presence of water, optionally after addition of water.

Claims (13)

1. A process for preparing 3(4), 8(9)-dihydroxymethyltricyclo[5.2.10 2,6 ]-decane comprising hydrogenating the hydroformylation products of dicyclopentadiene in the presence of water, optionally after addition of water, whereas the hydroformylation products of dicyclopentadiene are fed to the hydrogenation stage without further purification and without catalyst removal.

2. The process of claim 1 , wherein the water is added before or during hydrogenation.

3. The process of claim 1 , wherein water is added to the reaction mixture in the hydrogenation to a content of from 0.5 to 5.0% by weight, based on the total use amount.

4. The process of claim 1 , wherein the hydrogenation is effected in the presence of aliphatic alcohols.

5. The process of claim 1 , wherein the hydrogenation is carried out in the presence of nickel catalysts.

6. The process of claim 1 , wherein the hydrogenation is carried out at a temperature of from 70 to 170° C. and at a pressure of from 1 to 30 MPa.

7. The process of claim 1 , wherein the hydroformylation products of dicycylopentadiene are obtained by hydroformylation in homogeneous organic phase in the presence of homogeneously dissolved rhodium catalysts.

8. The process of claim 7 , wherein the hydroformylation is effected in the presence of water.

9. The process of claim 8 , wherein water is present in an amount of at least 0.1% by weight, based on the total use.

10. The process of claim 9 , wherein the water content is from 0.5 to 2.5% by weight, based on the total use.

11. The process of claim 9 wherein the water content is 1.0 to 2.0% by weight.

12. The process of claim 3 wherein the water is added to a content of 1.0 to 4.0% by weight.

13. The process of claim 10 wherein the amount of water is at least 0.5 by weight.

Assignments (6)
CHANGE OF NAME Recorded Apr 1, 2008
From: OXEA DEUTSCHLAND GMBH
To: OXEA GMBH
Reel/Frame 022856/0130 →
CORRECTIVE ASSIGNMENT TO CORRECT PROPERTY NUMBER 10/967,957, PREVIOUSLY RECORDED AT REEL 019588 FRAME 0313. Recorded Sep 26, 2007
From: CELANESE CHEMICALS EURORE GMBH
To: OXEA DEUTSCHLAND GMBH
Reel/Frame 019881/0260 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 13, 2007
From: CELANESE CHEMICALS EUROPE GMBH
To: OXEA DEUTSCHLAND GMBH
Reel/Frame 019588/0313 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 8, 2007
From: CALANESE CHEMICAL EUROPE GMBH
To: OXEA DEUTSCHLAND GMBH
Reel/Frame 019308/0246 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 27, 2007
From: CELANESE CHEMICALS EUROPE GMBH; CELANESE GMBH; HOECHST AG; CLARIANT GMBH
To: DRACHENFELSSEE 521. VV GMBH (TO BE RENAMED OXEA DEUTSCHLAND GMBH)
Reel/Frame 019069/0199 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 24, 2005
From: DUKAT, WOLFGANG; STORM, EDGAR; SCHMID, KLAUS
To: CELANESE CHEMICALS EUROPE GMBH
Reel/Frame 016737/0307 →