Concentrated, water-based dispersions for crop protection
View Patent ↗Liquid aqueous formulations of water-soluble active crop protectant ingredients which comprise (a) one or more water-soluble active crop protectant ingredients (type (a) ingredients), (b) one or more water-dispersed active crop protectant ingredients (type (b) ingredients), (c) one or more surfactants from the class of the polyacrylic acid derivatives, (d) one or more aluminum silicates as stabilizer(s), (e) if desired, further anionic or nonionic, cationic and/or zwitterionic surfactants, (f) if desired, other customary formulation assistants, and (g) water are suitable as stable coformulations for use in crop protection.
1. A liquid aqueous crop protectant composition which comprises as components (a) to (g):
(a) 1% to 60% by weight of one or more water-soluble active ingredients selected from the group consisting of the salts of glufosinate, glyphosate, paraquat, diquat, MCPA, CMPP, ioxynil, bromoxynil, 2,4-D, TCA, 2,4 DP and salts thereof,
(b) 0.5% to 30% by weight of water-insoluble active ingredient selected from the group consisting of oxyfluorfen, lactofen, bifenox, fluoroglycofen, fomesafen, diclofop-methyl, fenoxaprop-ethyl and fenoxaprop-P-ethyl,
(c) 0.05% to 15% by weight of one or more surfactants from the class of the polyacrylic acid derivatives,
(d) 0.05% to 15% by weight of one or more aluminum silicates as stabilizer(s),
(e) 0 to 80% by weight of nonionic, anionic, cationic and/or zwitterionic surfactants,
(f) 0 to 30% by weight of customary formulation assistants, and
(g) 0.1% to 90% by weight of water.
2. The crop protectant composition as claimed in claim 1 , comprising as a component (a) ingredient a salt of glufosinate.
3. The crop protectant composition as claimed in claim 2 , comprising as a component (a) ingredient glufosinate-ammonium.
4. The crop protectant composition as claimed in claim 1 , comprising as a component (b) ingredient an active ingredient selected from the group consisting of oxyfluorfen, lactofen, bifenox, fluoroglycofen, and fomesafen.
5. The crop protectant composition as claimed in claim 4 , comprising as a component (b) ingredient oxyfluorfen.
6. The crop protectant composition as claimed in claim 1 , wherein the weight ratio of component (a) to component (b) amounts to 15:1 to 1:12.
7. The crop protectant composition as claimed in claim 1 , wherein the weight ratio of surfactant (c) to aluminum silicate (d) amounts to 15:1 to 1:20.
8. The crop protectant composition as claimed in claim 1 , wherein component (a) is glufosinate ammonium and component (b) is oxyfluorfen.
9. The crop protectant composition as claimed in claim 1 , comprising as a component (b) ingredient an active ingredient selected from the group consisting of diclofop-methyl, fenoxaprop-ethyl and fenoxaprop-P-ethyl.
10. The crop protectant composition as claimed in claim 1 , wherein the composition is an aqueous suspension wherein any organic solvent present is miscible with water or no organic solvent is present.
11. The crop protectant composition as claimed in claim 10 , which comprises
(a) 5% to 55% by weight of water-soluble active ingredients of component (a),
(b) 1% to 20% by weight of water-insoluble active ingredients of component (b),
(c) 0.1% to 10% by weight of surfactants from the class of the polyacrylic acid derivatives,
(d) 0.1% to 8% by weight of aluminum silicates as stabilizer(s),
(e) 0 to 70% by weight of nonionic, anionic, cationic and/or zwitterionic surfactants,
(f) 0 to 20% by weight of customary formulation assistants, and
(g) 5% to 70% by weight of water.
12. The crop protectant composition as claimed in claim 11 , wherein the weight ratio of component (a) to component (b) amounts to 15:1 to 1:12.
13. The crop protectant composition as claimed in claim 12 , wherein the weight ratio of surfactant (c) to aluminum silicate (d) amounts to 15:1 to 1:20.
14. The crop protectant composition as claimed in claim 13 , comprising as a component (a) ingredient a salt of glufosinate.
15. The crop protectant composition as claimed in claim 14 , comprising as a component (a) ingredient glufosinate-ammonium.
16. The crop protectant composition as claimed in claim 15 , comprising as a component (b) ingredient oxyfluorfen.
17. The crop protectant composition as claimed in claim 11 , wherein component (a) is glufosinate ammonium and component (b) is oxyfluorfen.
18. A process for preparing a crop protectant composition as defined in claim 1 , which comprises mixing components (a) to (f) and any further components present in the formulation with water (component (g)).
19. A method of controlling unwanted plant growth, which comprises applying an effective amount of a crop protectant composition as claimed in claim 1 , comprising at least one active herbicidal ingredient, to the plants, parts of plants or the cultivation area.
20. A method of controlling a pest which comprises applying an effective amount of a crop protectant composition as claimed in claim 1 and comprising active ingredients effective against such pests, to the cultivation area or the non-crop area where the pest occurs.