Photothermographic material and image forming method
Provided are a photothermographic material which includes, on at least one side of a support, an image forming layer containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder, and is X-ray exposed with a fluorescent intensifying screen, wherein (1) the photosensitive silver halide includes tabular grains having a mean aspect ratio of 2 to 100 and a mean equivalent spherical diameter of 0.3 μm to 10 μm, (2) an exposure value necessary for obtaining an image density of fog+0.5 after exposing the photothermographic material with monochromatic light having the same wavelength as the main emission peak wavelength of the fluorescent intensifying screen and having a half width of 15 nm±5 nm and thermally developing the photothermographic material is from 1×10 −6 watt·sec·m −2 to 1×10 −3 watt·sec·m −2 , and (3) haze of the photothermographic material after thermal devolpment is less than 80% of that before thermal development; and an image forming method using the same.
1. A photothermographic material used for a method of forming an image, which comprises performing X-ray imagewise exposure with a fluorescent intensifying screen and thermal development, wherein the photothermographic material comprising: on at least one side of a support, an image forming layer comprising at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder, wherein
(1) the photosensitive silver halide comprises tabular grains having a mean aspect ratio of 2 to 100 and a mean equivalent spherical diameter of 0.3 μm to 10 μm,
(2) an exposure value necessary for obtaining an image density of fog+0.5 after exposing the photothermographic material with monochromatic light having the same wavelength as the main emission peak wavelength of the fluorescent intensifying screen and having a half width of 15 nm±5 nm and thermally developing the photothermographic material is from 1×10 −6 watt·sec·m −2 to 1×10 −3 watt·sec·m −2 , and
(3) haze of the photothermographic material after thermal devolpment is less than 80% of that before thermal development.
2. The photothermographic material according to claim 1 , wherein the fluorescent intensifying screen includes a fluorescent substance, and 50% or more of emission light of the fluorescent substance has a wavelength of 350 nm to 420 nm.
3. The photothermographic material according to claim 2 , wherein the fluorescent substance contains a divalent Eu-activated fluorescent substance.
4. The photothermographic material according to claim 3 , wherein the fluorescent substance contains a divalent Eu-activated barium halide fluorescent substance.
5. The photothermographic material according to claim 1 , wherein the haze after thermal development is less than 75% of that before thermal development.
6. The photothermographic material according to claim 1 , wherein an amount of coated silver of the photosensitive silver halide is from 0.04 g/m 2 to 0.4 g/m 2 per one side of the support.
7. The photothermographic material according to claim 1 , further comprising a nucleator, wherein an average gradient of a photographic characteristic curve is 1.8 to 5.0.
8. The photothermographic material according to claim 7 , wherein the nucleator is a compound selected from the group consisting of a hydrazine derivative compound, a vinyl compound, a quaternary onium compound, and an olefin compound.
9. The photothermographic material according to claim 1 , wherein an NH 4 + content of the photothermographic material is 1 mmol/m 2 or less per one side of the support.
10. The photothermographic material according to claim 9 , wherein the NH 4 + content of the photothermographic material is 0.3 mmol/m 2 or less per one side of the support.
11. The photothermographic material according to claim 1 , wherein an average silver iodide content of the photosensitive silver halide is 40 mol % or higher.
12. The photothermographic material according to claim 11 , wherein the average silver iodide content of the photosensitive silver halide is 80 mol % or higher.
13. The photothermographic material according to claim 12 , wherein the average silver iodide content of the photosensitive silver halide is 90 mol % or higher.