Process for producing alcohol
View Patent ↗The invention relates to a process for producing an alcohol including hydrogenating an aldehyde using a hydrogenation catalyst and subjecting the resultant product to distillation/purification, wherein the resultant hydrogenation product is subjected to distillation/purification in the absence of the hydrogenation catalyst or in the presence of the hydrogenation catalyst in such an amount that does not cause a dehydrogenation reaction.
1. A process for producing a purified alcohol, the process comprising
hydrogenating an aldehyde in a reactor packed with a hydrogenation catalyst to form a crude alcohol, and
purifying the crude alcohol by distillation to produce the purified alcohol;
wherein the hydrogenation reaction is carried out in the liquid phase,
wherein, during the hydrogenation process, some of the packed hydrogenation catalyst escapes into the reaction solution in the form of a powder,
wherein most of the powdered hydrogenation catalyst is removed from the reaction solution via filtration after the hydrogenation of the aldehyde and before distillation of the crude alcohol
wherein the crude alcohol is subjected to distillation/purification in the presence of the remaining powdered hydrogenation catalyst
such that a dehydrogenation reaction of the alcohol to the aldehyde is suppressed,
wherein the aldehyde contained in the purified alcohol, after distillation/purification, is 0.05 wt% or less, and
wherein the amount of the powdered catalyst present during the distillation/purification of the crude alcohol is present in a positive amount of 100 ppm or less.
2. The process of claim 1 , wherein a conversion rate of the aldehyde is 98% or more in the hydrogenation step.
3. The process of claim 1 , wherein a conversion rate of the aldehyde to the crude alcohol is 99.99%.
4. The process of claim 1 , wherein the aldehyde comprises 3 to 10 carbon atoms.
5. The process of claim 4 , wherein the aldehyde is formed by hydroformylation of an olefin.
6. The process of claim 1 , wherein the hydrogenation is carried out at a temperature of from 40 to 200° C.
7. The process of claim 1 , wherein the pressure during the hydrogenation reaction ranges from 1 to 150 atm.
8. The process of claim 1 , wherein the purified alcohol has an aldehyde concentration of 50 wt ppm or less.
9. The process of claim 1 , wherein the catalyst comprises an active component, and wherein the active component comprises at least metal selected from the group consisting of nickel, chromium, and copper.
10. The process of claim 9 , wherein the active component of the catalyst is supported on diatomaceous earth.
11. The process of claim 9 , wherein the active component of the catalyst is supported on celite.
12. The process of claim 1 , wherein the aldehyde is butyraldehyde.
13. The process of claim 1 , wherein the aldehyde is heptyl aldehyde.
14. The process of claim 1 , wherein the aldehyde is nonylaldehyde.
15. The process of claim 1 , wherein the aldehyde is propionaldehyde.
16. The process of claim 1 , wherein the aldehyde is undecyl aldehyde.
17. The process of claim 1 , wherein the aldehyde is tridecyl aldehyde.
18. The process of claim 1 , wherein the aldehyde is hexadecyl aldehyde.
19. The process of claim 1 , wherein the aldehyde is 2-ethylhexenal.