Optical device comprising an optical component and an optical medium with different refractive indices
View Patent ↗The present invention consists in an optical device comprising an optical component and an optical medium with different refractive indices, said optical component being at least partly immersed in said optical medium, which device is characterized in that said optical medium contains a salt that is in the liquid state in the range of temperatures at which said optical component is used and stored, i.e. in a range of temperatures generally from −40° C. to +200° C. The optical component may in particular be a Bragg long-period grating (LPG) or a photonic crystal fiber.
1. An optical device, comprising an optical component and an optical medium that have different refractive indices, and wherein the optical properties of the optical component depend at least in part on the optical medium, said optical medium being external to said optical component and comprising one of (i) a salt that in the absence of a solvent is itself in the liquid state in the range of temperatures at which said optical component is used and stored or (ii) a mixture of salts that in the absence of a solvent other than one of said salts is itself in the liquid state in the range of temperatures at which said optical component is used and stored, and said optical component being at least partly immersed in said optical medium.
2. A device according to claim 1 , wherein said range of temperatures is from −40° C. to +200° C.
3. A device according to claim 1 , wherein said range of temperatures is from −40° C. to +85° C.
4. A device according to claim 1 , wherein said range of temperatures is from −20° C. to +120° C.
5. A device according to claim 1 , wherein said range of temperatures is from −10° C. to +70° C.
6. A device according to claim 1 , wherein said medium consists of a mixture of at least two salts.
7. A device according to claim 6 , wherein said mixture contains a first salt in the liquid state and a second salt dissolved in said first salt.
8. A device according to claim 6 , wherein the composition of said mixture remains stable over time.
9. A device according to claim 1 , wherein said salt or a salt of said mixture of salts contains an anion and a cation.
10. A device according to claim 9 , wherein said anion is selected from a fluoride F—, a chloride Cl—, a bromide Br—, an iodide I—, an aluminochlorate AlClO 4 —, a perchlorate ClO 4 —, a tetrafluoroborate BF 4 —, a hexafluorophosphate PF 6 —, a hexafluoroarsenate AsF 6 —, a hydrogenosulfate HSO 4 —, a trifluoroacetate CF 3 COO—, a heptafluoro-1-butanoate C 3 F 7 COO—, a trifluoromethanesulfonate CF 3 SO 3 — (or “triflate” TfO—), a nonafluorobutylsulfonate C 4 F 9 SO 3 — (or “nonaflate” NfO—), a bis-trifluoromethanesulfonimide N(CF 3 SO 2 ) 2 — (or Tf 2 N—), and a bis-trifluoromethanesulfonemethide C(CF 3 SO 2 ) 2 — (or Tf 2 C—).
11. A device according to claim 9 , wherein said cation is selected from ammonium NH 4 +, sulfonium HSO 3 +, phosphonium PH 4 +, lithium Li+, pyridinium C 5 H 5 NH+, imidazolium cations (C 3 H 6 N 2 X 1 X 2 )+, ammonium cations (X 1 X 2 X 3 X 4 N 4 )+, sulfonium cations (X 1 X 2 X 3 S)+, phosphonium cations (X 1 X 2 X 3 X 4 P)+, and pyridinium cations (X 1 C 5 H 4 NX 2 )+, where X 1 , X 2 , X 3 , X 4 represent aromatic or aliphatic groups.
12. A device according to claim 9 , wherein said salt or said salt of said mixture of salts has for the cation N,N′ dialkylimidazolium with the following general formula, in which R 1 and R 2 are aliphatic or aromatic groups containing an anion:
13. A device according to claim 12 , where R 1 and R 2 are similar or different and each contains an anion selected from F—, Cl—, Br—, I—, BF 4 —, PF 6 —, AsF 6 , ClO 4 —, AlClO 4 —, CF 3 COO—, C 3 F 7 COO—, CF 3 SO 3 —, C 4 F 9 SO 3 —, (CF 3 SO 2 ) 2 N—, (CF 3 SO 2 ) 2 C—.
14. A device according to claim 12 , wherein R 1 and R 2 are similar or different and are an aliphatic group selected from methyl —CH 3 , ethyl —C 2 H 6 , propyl —C 3 H 7 and butyl —C 4 H 9 .
15. A device according to claim 14 , wherein said salt or said salt of said mixture contains an anion selected from Cl—, Br—, PF 6 —, BF 4 —, (CF 3 SO 2 ) 2 N—, and C 4 F 9 SO 3 —.
16. A device according to claim 1 , wherein said optical component is a Bragg long-period grating (LPG).
17. A device according to claim 16 , wherein said grating is tuned by modifying the immersion of the optical component in said medium.
18. A device according to claim 16 , wherein the optical response of said grating is substantially constant over said range of temperatures.
19. A device according to claim 18 , wherein said range of temperatures is from −10° C. to +70° C.
20. A device according to claim 1 , wherein said optical component is a length of photonic crystal fiber.
21. A device according to claim 20 , comprising a temperature control unit for controlling the value of the refractive index of the medium.
22. A device according to claim 21 , wherein the temperature control unit is adapted to subject said medium to a temperature from −20° C. to +120° C.
23. A device according to claim 1 , wherein said salt or mixture of salts comprises a room temperature ionic liquid.
24. A device according to claim 1 , wherein said optical medium consists of said salt or mixture of salts.
25. A device according to claim 1 , wherein said medium comprises a salt that in the absence of a solvent is itself in the liquid state over said range of temperatures.
26. A device according to claim 25 , wherein said optical medium comprises a mixture of salts.
27. A device according to claim 25 , wherein said salt has a melting temperature below said range of temperatures.
28. A device according to claim 25 , wherein said salt has a melting temperature no greater than −10°C.