Catalytic reactive separation system for energy-efficient production of cumene
View Patent ↗The present invention relates to an atmospheric pressure, reactive separation column packed with a solid acid zeolite catalyst for producing cumene from the reaction of benzene with propylene. Use of this un-pressurized column, where simultaneous reaction and partial separation occur during cumene production, allow separation of un-reacted, excess benzene from other products as they form. This high-yielding, energy-efficient system allows for one-step processing of cumene, with reduced need for product purification. Reacting propylene and benzene in the presence of beta zeolite catalysts generated a selectivity greater than 85% for catalytic separation reactions at a reaction temperature of 115 degrees C and at ambient pressure. Simultaneously, up to 76% of un-reacted benzene was separated from the product; which could be recycled back to the reactor for re-use.
1. A catalytic reactive separation system for the production of cumene, comprising:
a reactive separation column, comprising:
a packed, solid-acid catalyst bed having a vertical height greater than about ½ inch, and less than about 2 inches, held in place inside of the column by upper and lower porous supports;
a lower zone located below the catalyst bed comprising glass beads;
an upper zone located above the catalyst bed comprising glass beads;
an open volume located above the upper zone of glass beads; and
means for heating or cooling at least part of the column;
first injection means for injecting propylene gas into the catalyst bed from outside the column;
second injection means for injecting liquid benzene into the catalyst bed from outside the column;
means for removing un-reacted liquid benzene, liquid cumene, and other heavy products from the bottom of the column;
benzene condenser means for condensing un-reacted benzene vapor that exits from the top of the column;
benzene accumulator means for accumulating the condensed benzene vapor;
reboiler means for evaporating un-reacted liquid benzene collected from the bottom of the column and returning the evaporated benzene back to the column;
cumene receiver means for storing the liquid cumene and other heavy products that exit from the bottom of the column;
recycle means for recycling un-reacted liquid benzene from the benzene accumulator means back into the reactive separation column the second injection means; and
wherein the first injection means for injecting propylene gas into the catalyst bed and the second injection means for injecting liquid benzene into the catalyst bed are both located at the same vertical height along the column.
2. The catalytic reactive separation system of claim 1 , wherein the packed catalyst bed comprises a solid-acid catalyst material selected from the group consisting of powders of protonated (H + β) beta-zeolite (Si:Al 2 25:1), pellets of 80% β beta-zeolite (Si:Al 2 24:1) mixed with 20% alumina binder, MCM-22 zeolite, ZSM-5 zeolite, and USY catalyst.
3. The catalytic reactive separation system of claim 1 , wherein the catalyst bed comprises beta-zeolite doped with about 1 wt% of a metal selected from the group consisting of gallium, platinum, lanthanum, and cerium.
4. The catalytic reactive separation system of claim 1 , wherein the reboiler means is heated to a temperature greater than or equal to about 80degrees C, and less than or equal to about 152 degrees C.
5. The catalytic reactive separation system of claim 1 , wherein the catalyst bed is heated to a temperature greater than or equal to about 80degrees C, and less than or equal to about 152 degrees C.
6. The catalytic reactive separation system of claim 1 , wherein the entire vertical height of the column is heated to a temperature greater than or equal to about 80 degrees C, and less than or equal to about 152 degrees C.
7. The catalytic reactive separation system of claim 1 , wherein the catalyst bed is heated to a temperature equal to about 115 degrees C.
8. The catalytic reactive separation system of claim 1 , wherein the reactive separation column is operated at atmospheric pressure, and is not constructed as a pressure vessel, and cannot be pressurized above ambient pressure.
9. The catalytic reactive separation system of claim 1 , wherein the vertical height of the packed catalyst bed is about 1 inch.
10. The catalytic reactive separation system of claim 1 , wherein the packed catalyst bed does not comprise any structured catalyst assemblies.
11. The catalytic reactive separation system of claim 1 , further comprising makeup means for supplying makeup liquid benzene to the reactive separation column.
12. The catalytic reactive separation system of claim 1 , wherein means for heating or cooling at least part of the column comprises external heating means selected from the group consisting of a electric resistance heating jacket wrapped around the outside of the column, and pipe means for circulating a heated or cooled gas or liquid around the outside of the column.
13. The catalytic reactive separation system of claim 1 , wherein the means for heating or cooling at least part of the column comprises internal heating means selected from the group consisting of an internal electric resistance heating element disposed inside of the catalyst bed, and internal pipe means for circulating a heated or cooled gas or liquid inside the catalyst bed.
14. The catalytic reactive separation system of claim 1 , wherein the system does not comprise means for pressurizing the reactive separation column above atmospheric pressure.
15. The catalytic reactive separation system of claim 1 , wherein the reactive separation column is vented to the ambient environment.
16. The catalytic reactive separation system of claim 1 , wherein both the propylene gas and the liquid benzene are injected into the middle of the catalyst bed from outside the column.
17. The catalytic reactive separation system of claim 1 , wherein both the propylene gas and the liquid benzene are injected into the bottom of the catalyst bed from outside the column.
18. A method of producing cumene, comprising:
a) providing the catalytic reactive separation system of claim 1 ;
b) heating the catalyst bed to a temperature greater than or equal to about 80 degrees C, and less than or equal to about 152 degrees C;
c) maintaining the pressure inside the reactive separation column at or below atmospheric pressure;
d) injecting propylene gas into the heated catalyst bed via the first injection means;
e) injecting liquid benzene into the heated catalyst bed via the second injection means;
f) producing cumene by reacting propylene and benzene in the presence of the solid-acid catalyst material;
g) removing un-reacted liquid benzene, liquid cumene, and other heavy products from the bottom of the column;
h) evaporating un-reacted liquid benzene collected from the bottom of the column and returning the evaporated benzene back to the column;
i) condensing un-reacted benzene vapor that exits from the top of the column; and
j) recycling the condensed un-reacted benzene vapor back into the reactive separation Column via the second injection means.
19. The method of producing cumene of claim 18 , wherein step j) comprises recycling the condensed un-reacted benzene vapor back into the packed catalyst bed.