System and method for producing metal powder by electrowinning
View Patent ↗This invention relates to a system and method for producing a metal powder product using either conventional electrowinning or alternative anode reaction chemistries in a flow-through electrowinning cell. The present invention enables the production of high quality metal powders, including copper powder, from metal-containing solutions using conventional electrowinning processes, direct electrowinning, or alternative anode reaction chemistries.
1. A process for producing copper powder by electrowinning comprising the steps of:
introducing a copper-containing solution into a flow-through electrowinning cell;
electrowinning copper powder from said copper-containing solution to produce a slurry stream containing copper powder particles and electrolyte; wherein said step of electrowinning copper powder comprises oxidizing ferrous iron at an anode to form ferric iron and forming copper powder at a cathode.
2. The process of claim 1 , further comprising the step of separating at least a portion of the electrolyte from the copper powder particles in the slurry stream.
3. The process of claim 2 , further comprising the step of conditioning at least a portion of said slurry stream
4. The process of claim 3 , further comprising the step of conditioning at least a portion of said slurry stream to stablilize at least a portion of said slurry stream.
5. The process of claim 3 , wherein said step of conditioning comprises contacting at least a portion of said slurry with a stabilizing agent.
6. The process of claim 3 , wherein said step of conditioning comprises contacting at least a portion of said slurry with an organic surfactant and a stabilizing agent.
7. The process of claim 3 , further comprising the step of conditioning at least a portion of said slurry stream to remove contaminants and/or impurities contained in the residual entrained electrolyte.
8. The process of claim 3 , further comprising the step of drying the copper powder particles originally present in the slurry stream to produce a copper powder product.
9. The process of claim 1 , further comprising the step of subjecting said copper powder product to at least one of size classification, packaging, direct forming, casting, briquetting, extrusion or melting.
10. The process of claim 1 , further comprising the steps of:
washing at least a portion of the copper powder particles in said slurry stream to produce a process solution stream, and
separating at least a portion of said process solution stream from said copper powder particles.
11. A process for producing copper powder by electrowinning consisting essentially of:
introducing a copper-containing solution into a flow-through electrowinning cell;
electrowinning copper powder from a copper-containing solution to produce a slurry stream containing copper powder particles and electrolyte, wherein said step of electrowinning copper powder comprises oxidizing ferrous iron at an anode to form ferric iron and forming copper powder at a cathode;
optionally, separating at least a portion of the electrolyte from the copper powder particles in the slurry stream;
optionally, separating at least a portion of the coarse copper powder particles in said slurry stream from at least a portion of the fine copper powder particles in said slurry stream in a size classification stage;
conditioning at least a portion of said slurry stream;
optionally, separating at least a portion of the bulk liquid from the copper powder particles in said slurry stream;
optionally, drying at least a portion of the copper powder particles originally present in the slurry stream to produce a copper powder product; and
optionally, subjecting said copper powder product to at least one of size classification, packaging, direct forming, casting, briquetting, extrusion or melting.
12. The process of claim 11 , wherein said step of conditioning comprises contacting at least a portion of said slurry with a stabilizing agent.
13. The process of claim 11 , wherein said step of conditioning comprises contacting at least a portion of said slurry with an organic surfactant and a stabilizing agent.