Method of manufacturing a reference electrode
View Patent ↗A method of manufacturing a reference electrode which has a shaft into which a diaphragm body of a porous ceramic is incorporated is comprised of the following method steps: Impregnating the ceramic with a lyogel precursor prior to incorporating the ceramic body into the shaft, and subsequently transforming the lyogel precursor into a lyogel, from which the solvent is removed through a drying process. A reference electrode has a shaft that is filled with electrolyte, and a diaphragm body formed of a porous ceramic and containing a system of hollow spaces is incorporated into the wall of the shaft. The system of hollow spaces is filled at least partially with a material that is formed of a lyogel by drying and has at least one component that corresponds to the ceramic material.
1. A method of manufacturing a reference electrode, the reference electrode having a shaft into which a diaphragm body of a porous ceramic is incorporated, the method comprising the steps of:
providing a porous ceramic body;
impregnating the ceramic body with a lyogel precursor;
transforming the lyogel precursor into a lyogel;
removing solvent from the impregnation step by drying, to form the diaphragm body; and
incorporating the diaphragm body into the shaft.
2. The method of claim 1 , wherein the drying process transforms the lyogel into an aerogel.
3. The method of claim 2 , wherein the porous ceramic comprises zirconia.
4. The method of claim 3 , wherein the porous ceramic further comprises at least one of calcium oxide, magnesium oxide and yttrium oxide as a stabilizing additive.
5. The method of claim 4 , wherein the lyogel precursor is an aqueous suspension of nano particles selected from the group consisting of zirconia, zirconia/calcia, zirconia/magnesia, and zirconia/yttria.
6. The method of claim 4 , wherein the lyogel precursor is selected from a group consisting of an aqueous zirconium solution, an organic zirconyl compound and a zirconium compound in an organic solvent.
7. The method of claim 4 , wherein the step of transforming the lyogel precursor into the lyogel occurs by a change of the pH value.
8. The method of claim 7 , wherein a base is used to change the pH value.
9. The method of claim 8 , wherein the base is an ammonia solution.
10. The method of claim 8 , wherein the base is a volatile organic amine.
11. The method of claim 8 , wherein the base is used in a gaseous state.
12. The method of claim 8 , wherein the base is selected from the group consisting of isopropylamine, propylamine, tetramethyl amino methane, and triethylamine.
13. The method of claim 1 , wherein the lyogel precursor used to impregnate the porous ceramic includes a gelating agent.
14. The method of claim 1 , wherein the porous ceramic comprises zirconia.
15. The method of claim 14 , wherein the porous ceramic further comprises at least one of calcium oxide, magnesium oxide and yttrium oxide as a stabilizing additive.
16. The method of claim 1 , wherein the lyogel precursor is an aqueous suspension of nano particles selected from the group consisting of zirconia, zirconia/calcia, zirconia/magnesia, and zirconia/yttria.
17. The method of claim 1 , wherein the lyogel precursor is selected from a group consisting of an aqueous zirconium solution, an organic zirconyl compound and a zirconium compound in an organic solvent.
18. The method of claim 1 , wherein the step of transforming the lyogel precursor into the lyogel occurs by a change of the pH value.
19. The method of claim 18 , wherein a base is used to change the pH value.
20. The method of claim 19 , wherein the base is an ammonia solution.
21. The method of claim 19 , wherein the base is a volatile organic amine.
22. The method of claim 19 , wherein the base is selected from the group consisting of isopropylamine, propylamine, tetramethyl amino methane, and triethylamine.
23. The method of claim 19 , wherein the base is used in a gaseous state.
24. A reference electrode comprising: a shaft adapted to be filled with electrolyte, a wall of the shaft having a diaphragm body incorporated therein, the diaphragm body being formed of a porous ceramic and providing a system of hollow spaces wherein the system of hollow spaces is filled at least partially with a material formed of a lyogel by drying, the material comprising at least one component that corresponds to the ceramic material.
25. The reference electrode according to claim 24 , wherein the ceramic is formed of zirconia.
26. The reference electrode of claim 25 , wherein the lyogel is selected from at least one of zirconia, zirconia/calcia, zirconia/magnesia, and zirconia/yttria.
27. The reference electrode of claim 24 , wherein the lyogel is selected from at least one of zirconia, zirconia/calcia, zirconia/magnesia, and zirconia/yttria.