IP Library Granted Patent US 8,137,658
Granted Patent B2
US 8,137,658 · App. 11/168,163 · Granted Mar 20, 2012

Tooth whitening compositions

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Quick Facts
Patent No.
US 8,137,658
App. No.
11/168,163
Granted
Mar 20, 2012
Kind
B2
Abstract

A liquid, substantially anhydrous tooth whitener composition for delivery of a tooth-whitening amount of active whitening ingredient onto teeth, with effective bioadhesion and retention thereof, and, thereupon, sufficient penetration of the ingredient through the tooth enamel, providing efficacious bleaching of stained teeth.

Claims (11)

1. A liquid, substantially anhydrous tooth whitener composition for delivery of a tooth-whitening amount of active whitening ingredient onto teeth, with effective bioadhesion and retention thereof, and, thereupon, sufficient penetration of said ingredient through the tooth enamel, providing efficacious bleaching of stained teeth, comprising, by weight,

(a) 10% to 75% of a complex which is (i) a mixture of 78 to 90% of water soluble polyvinylpyrrolidone (PVP) having K-values of K-12 to K-120 and (ii) 10 to 22% of H 2 O 2 ; releasing 1 to 20% of active H 2 O 2 from said complex onto a tooth surface;

(b) 0 to 20% of PVP K-60 to K-90, said PVP being present in said composition at a K-value of the PVP in said complex of less than 30, and/or the amount of PVP therein is less than 20%, and

(c) 30 to 90% of anhydrous ethanol, said composition having a Brookfield viscosity measured at 25° C. of 50 to 10,000 cps, an in vitro bioadhesion/retention on hydroxyapatite (HAP) of at least 10% after 5 minutes while immersed in water, and a bleaching efficacy defined by ΔE values in the CIE (L*a*b*) color scale of at least 5.

2. A tooth whitener composition according to claim 1 wherein the PVP in (a) is PVP K-30.

3. A tooth whitener composition according to claim 1 wherein the PVP in (b) is PVP K-90.

4. A tooth whitener composition according to claim 1 wherein the PVP in (a) is K-90.

5. A tooth whitener composition according to claim 1 wherein said amount of in (c) is 65 to 80%.

6. A tooth whitener composition according to claim 1 having a viscosity measured at 25° C. of 75-1500 cps.

7. A tooth whitener composition according to claim 6 having a viscosity measured at 25° C. of 100 to 800 cps.

8. A tooth whitener composition according to claim 1 wherein the amount of said complex comprises: (a) 20 to 60%, and (b) 0.1-10%.

Assignments (5)
RELEASE OF SECURITY INTEREST Recorded Jan 10, 2020
From: THE BANK OF NOVA SCOTIA
To: AVOCA LLC; HERCULES LLC; ISP INVESTMENTS LLC; PHARMACHEM LABORATORIES LLC
Reel/Frame 051557/0504 →
SECURITY AGREEMENT Recorded Jul 3, 2017
From: AVOCA, INC.; HERCULES LLC; ISP INVESTMENTS LLC; PHARMACHEM LABORATORIES, INC.
To: THE BANK OF NOVA SCOTIA, AS ADMINISTRATIVE AGENT
Reel/Frame 043084/0753 →
RELEASE OF PATENT SECURITY AGREEMENT Recorded Mar 18, 2013
From: THE BANK OF NOVA SCOTIA
To: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; AQUALON COMPANY; ISP INVESTMENTS INC.; HERCULES INCORPORATED
Reel/Frame 030025/0320 →
PATENT RELEASE Recorded Sep 19, 2011
From: JPMORGAN CHASE BANK, N.A. (F/K/A THE CHASE MANHATTAN BANK)
To: ISP CAPITAL, INC.; ISP CHEMICAL PRODUCTS, INC.; VERONA, INC.
Reel/Frame 026930/0774 →
SECURITY AGREEMENT Recorded Sep 16, 2011
From: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; HERCULES INCORPORATED; AQUALON COMPANY; ISP INVESTMENT INC.
To: THE BANK OF NOVA SCOTIA, AS ADMINISTRATIVE AGENT
Reel/Frame 026918/0052 →