IP Library Granted Patent US 7,686,906
Granted Patent B2
US 7,686,906 · App. 11/170,445 · Granted Mar 30, 2010

Methods of making polymer interlayers comprising poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester

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Quick Facts
Patent No.
US 7,686,906
App. No.
11/170,445
Granted
Mar 30, 2010
Kind
B2
Abstract

The present invention is in the field of polymer interlayers used in multiple layer glass panels having one or more glass layers, and specifically the present invention is in the field of polymer interlayers comprising a layer of poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester (PETG).

Claims (34)

1. A method of manufacturing a multiple layer glazing panel interlayer, comprising:

forming a first melt comprising poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester;

forming a second melt comprising polyurethane or poly(ethylene-co-vinyl acetate); and,

coextruding said first melt and said second melt to form said interlayer.

2. The method of claim 1 , wherein said second melt comprises poly(ethylene-co-vinyl acetate).

3. The method of claim 2 , wherein said poly(ethylene-co-vinyl acetate) is extruded at a temperature of 90° C. to 200° C. and said poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester is extruded at a temperature of 200° C. to 290° C.

4. The method of claim 2 , wherein said first melt is used to form a single layer and said second melt is used to form a single layer, thereby resulting in said interlayer having two layers.

5. The method of claim 2 , wherein said first melt is used to form a single layer and said second melt is used to form two layers, thereby resulting in said interlayer having a single layer of polymer comprising poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester disposed between two layers of polymer comprising poly(ethylene-co-vinyl acetate).

6. The method of claim 1 , wherein said second melt comprises polyurethane.

7. The method of claim 6 , wherein said polyurethane is extruded at a temperature of 150° C. to 225° C. and said poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester is extruded at a temperature of 200° C. to 290° C.

8. The method of claim 6 , wherein said first melt is used to form a single layer and said second melt is used to form a single layer, thereby resulting in said interlayer having two layers.

9. The method of claim 6 , wherein said first melt is used to form a single layer and said second melt is used to form two layers, thereby resulting in said interlayer having a single layer of polymer comprising poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester disposed between two layers of polymer comprising polyurethane.

10. The method of claim 1 , wherein said first polymer melt comprises poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester having at least 10% poly(ethylene terephthalate) component by weight.

11. The method of claim 1 , wherein said first polymer melt comprises poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester having at least 40% poly(ethylene terephthalate) component by weight.

12. A method of manufacturing a multiple layer glazing panel, comprising:

forming a first melt comprising poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester;

forming a second melt comprising polyurethane or poly(ethylene-co-vinyl acetate);

coextruding said first melt and said second melt to form an interlayer; and,

laminating said interlayer with at least one layer of glass to form said glazing panel.

13. The method of claim 12 , wherein said second melt comprises poly(ethylene-co-vinyl acetate).

14. The method of claim 13 , wherein said poly(ethylene-co-vinyl acetate) is extruded at a temperature of 90° C. to 200° C. and said poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester is extruded at a temperature of 200° C. to 290° C.

15. The method of claim 13 , wherein said first melt is used to form a single layer and said second melt is used to form a single layer, thereby resulting in said interlayer having two layers.

16. The method of claim 13 , wherein said first melt is used to form a single layer and said second melt is used to form two layers, thereby resulting in said interlayer having a single layer of polymer comprising poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester disposed between two layers of polymer comprising poly(ethylene-co-vinyl acetate).

17. The method of claim 12 , wherein said second melt comprises polyurethane.

18. The method of claim 17 , wherein said polyurethane is extruded at a temperature of 150° C. to 225° C. and said poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester is extruded at a temperature of 200° C. to 290° C.

19. The method of claim 17 , wherein said first melt is used to form a single layer and said second melt is used to form a single layer, thereby resulting in said interlayer having two layers.

20. The method of claim 17 , wherein said first melt is used to form a single layer and said second melt is used to form two layers, thereby resulting in said interlayer having a single layer of polymer comprising poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester disposed between two layers of polymer comprising polyurethane.

21. The method of claim 12 , wherein said first polymer melt comprises poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester having at least 10% poly(ethylene terephthalate) component by weight.

22. The method of claim 12 , wherein said first polymer melt comprises poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester having at least 40% poly(ethylene terephthalate) component by weight.

23. The method of claim 12 , wherein said interlayer is laminated between two layers of glass to form said glazing panel.

24. A multiple layer glazing panel interlayer produced by the process comprising:

forming a first melt comprising poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester;

forming a second melt comprising polyurethane or poly(ethylene-co-vinyl acetate); and,

coextruding said first melt and said second melt to form said interlayer.

Assignments (7)
RELEASE OF SECURITY INTEREST Recorded Jul 17, 2012
From: DEUTSCHE BANK TRUST COMPANY AMERICAS, AS COLLATERAL AGENT
To: SOLUTIA INC.; CPFILMS INC.; FLEXSYS AMERICA L.P.
Reel/Frame 028563/0241 →
SECURITY AGREEMENT Recorded May 17, 2010
From: SOLUTIA INC.; CP FILMS INC.; FLEXSYS AMERICA L.P.
To: DEUTSCHE BANK TRUST COMPANY AMERICAS, AS COLLATERAL AGENT
Reel/Frame 024390/0281 →
RELEASE OF TERM LOAN SECURITY INTEREST IN PATENTS - REEL/FRAME 022610/0697 Recorded Mar 30, 2010
From: CITIBANK, N.A.
To: SOLUTIA INC.; CPFILMS INC.; FLEXSYS AMERICA L.P.
Reel/Frame 024151/0513 →
RELEASE OF ABL SECURITY INTEREST IN PATENTS - REEL/FRAME 022610/0495 Recorded Mar 30, 2010
From: CITIBANK, N.A.
To: SOLUTIA INC.; CPFILMS INC.; FLEXSYS AMERICA L.P.
Reel/Frame 024151/0469 →
ABL PATENT SECURITY AGREEMENT Recorded Apr 29, 2009
From: SOLUTIA INC.; CPFILMS INC.; FLEXSYS AMERICA L.P.
To: CITIBANK, N.A.
Reel/Frame 022610/0495 →
TERM LOAN PATENT SECURITY AGREEMENT Recorded Apr 29, 2009
From: SOLUTIA INC.; CPFILMS INC.; FLEXSYS AMERICA L.P.
To: CITIBANK, N.A.
Reel/Frame 022610/0697 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 30, 2005
From: CHEN, WENJIE; SZYDLOWSKI, WITOLD; KARAGIANNIS, ARISTOTELIS
To: SOLUTIA INCORPORATED
Reel/Frame 016753/0306 →