Sinterable structures and method
View Patent ↗A method of producing an open, porous structure having an outer surface defining a shape having a bulk volume and having interconnecting openings extending throughout said volume and opening through said surface, and products resulting from the method. The method comprises preparing a viscous mixture comprising a sinterable powder dispersed in a sol of a polymer in a primary solvent, replacing the primary solvent with a secondary liquid in which the polymer is insoluble to produce a gel comprising an open polymeric network having the sinterable powder arranged therein, removing the secondary liquid from the gel; removing the polymer network, and sintering the sinterable powder to form the open, porous structure. Also disclosed are shaped, porous products resulting from methods of the invention.
1. Method of producing an open, porous structure having an outer surface defining a shape having a bulk volume and having interconnecting openings extending throughout said volume and opening through said surface comprising
a. preparing a viscous mixture comprising a sinterable powder dispersed in a sol of a polymer in a primary solvent, wherein the polymer weight per volume ratio of polymer to liquid in the sol is not greater than about 4.2:100 g/cc,
b. allowing said viscous mixture to fall into a secondary liquid in which the polymer is insoluble to replace said primary solvent with said secondary liquid and to produce a gel comprising an open polymeric network comprised of microfibrils and having said sinterable powder arranged therein,
c. removing said secondary liquid from said gel; and
d. sintering said sinterable powder to form said open, porous structure.
2. A flat, porous, rigid disc having an outer surface defining a shape having a bulk volume and having interconnecting openings extending throughout said volume in a reticulated, three dimensional configuration and opening through said surface, said article being formed by a method comprising forming into a predetermined shape a shapeable, viscous mixture comprising a sinterable powder comprised of particles dispersed in a sol of a polymer in a primary solvent, wherein the polymer weight per volume ratio of polymer to liquid in the sol is not greater than about 4.2:100 g/cc, allowing said sol in the primary solvent to fall into a secondary liquid in which the polymer is insoluble to produce a gel comprising an open polymeric network comprised of microfibrils and having said sinterable powder arranged therein with the positions of the particles guided by the positions of the microfibrils, removing said secondary liquid from the gel, and heating the gel to remove said polymeric network and to sinter said sinterable powder to form said shaped porous structure, the resulting reticulated, three dimensional configuration of the product following the position of the microfibrils.