Method for making a lithographic printing plate
View Patent ↗A method for making a lithographic printing plate is disclosed which comprises the steps of: (i) providing a negative-working, heat-sensitive lithographic printing plate precursor comprising a support having a hydrophilic surface or which is provided with a hydrophilic layer and a coating provided thereon, the coating comprising an image-recording layer which comprises hydrophobic thermoplastic polymer particles and a hydrophilic binder, wherein the hydrophobic thermoplastic polymer particles have an average particle size in the range from 45 nm to 63 nm and wherein the amount of the hydrophobic thermoplastic polymer particles in the image-recording layer is at least 70% by weight relative to the image-recording layer; (ii) exposing the coating to heat or infrared light, thereby inducing coalescence of the thermoplastic polymer particles at exposed areas of the coating; (iii) developing the precursor by applying an aqueous, alkaline solution, thereby removing non-exposed areas of the coating from the support, wherein the aqueous alkaline solution has a pH≧11 and comprises a phosphate buffer or a silicate buffer.
1. A method for making a lithographic printing plate comprising the steps of: (i) providing a heat-sensitive, negative-working printing plate precursor which is not sensitive to visible and UV light comprising a support with a hydrophilic surface or which comprises a hydrophilic layer and a coating provided thereon, the coating comprising an image-recording layer which comprises hydrophobic thermoplastic polymer particles and a hydrophilic binder, wherein the hydrophobic thermoplastic polymer particles have an average particle size in the range from 45 nm to 55 nm, and wherein the amount of the hydrophobic thermoplastic polymer particles in the image-recording layer is between 75% and 85% by weight relative to the weight of the image-recording layer; (ii) exposing the coating to heat or infrared light sufficient to induce coalescence of the thermoplastic polymer particles at exposed areas of the coating; and (iii) developing the precursor by applying an aqueous alkaline solution, thereby removing non-exposed areas of the coating from the support, wherein the aqueous alkaline solution has a pH≧11 and comprises a phosphate buffer or a silicate buffer.
2. The method for making a lithographic printing plate according to claim 1 wherein the aqueous alkaline solution further comprises a surfactant.
3. The method for making a lithographic printing plate according to claim 2 wherein the surfactant is non-ionic or amphoteric.
4. The method for making a lithographic printing plate according to claim 2 , wherein the hydrophobic thermoplastic polymer particles comprise polyethylene, poly(vinyl)chloride, polymethyl(meth)acrylate, polyethyl(meth)acrylate, polyvinylidene chloride, poly(meth)acrylonitrile, polyvinylcarbazole, polystyrene or copolymers thereof.
5. The method for making a lithographic printing plate according to claim 2 , wherein the hydrophobic thermoplastic polymer particles comprise polystyrene or a copolymer comprising polystyrene and poly(meth)acrylonitrile.
6. The method for making a lithographic printing plate according to claim 2 , wherein the hydrophilic binder is soluble in an aqueous developer having a pH≧10.
7. The method for making a lithographic printing plate according to claim 2 , wherein the image-recording layer further comprises an infrared absorbing agent in an amount of at least 6% by weight relative to the weight of the image-recording layer.
8. The method for making a lithographic printing plate according to claim 2 , wherein the coating further comprises one or more compound(s) which provide a visible image after image-wise exposure and development.
9. The method for making a lithographic printing plate according to claim 2 , wherein the coating further comprises at least one compound which provides a visible image afier image-wise exposure of the printing plate precursor but before development.
10. The method for making a lithographic printing plate according to claim 1 wherein the hydrophobic thermoplastic polymer particles comprise polyethylene, poly(vinyl)chloride, polymethyl(meth)acrylate, polyethyl(meth)acrylate, polyvinylidene chloride, poly(meth)acrylonitrile, polyvinylcarbazole, polystyrene or copolymers thereof.
11. The method for making a lithographic printing plate according to claim 1 wherein the hydrophobic thermoplastic polymer particles comprise polystyrene or a copolymer comprising polystyrene and poly(meth)acrylonitrile.
12. The method for making a lithographic printing plate according to claim 1 wherein the hydrophilic binder is soluble in an aqueous developer having a pH≧10.
13. The method for making a lithographic printing plate according to claim 1 wherein the image-recording layer further comprises an infrared absorbing agent in an amount of at least 6% by weight relative to the weight of the image-recording layer.
14. The method for making a lithographic printing plate according to claim 1 wherein the coating further comprises one or more compound(s) which provide a visible image afier image-wise exposure and development.
15. The method for making a lithographic printing plate according to claim 1 wherein the coating further comprises at least one compound which provides a visible image afier image-wise exposure of the printing plate precursor but before development.