IP Library Granted Patent US 7,597,963
Granted Patent B2
US 7,597,963 · App. 11/176,678 · Granted Oct 6, 2009

Insulating glass (IG) window unit including heat treatable coating with specific color characteristics and low sheet resistance

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Quick Facts
Patent No.
US 7,597,963
App. No.
11/176,678
Granted
Oct 6, 2009
Kind
B2
Abstract

An insulating glass (IG) window unit, or other suitable window unit, includes a glass substrate with a coating thereon. The coating includes a lower contact layer based on zinc oxide and/or at least one silicon nitride inclusive layer that is Si-rich (i.e., non-stoichiometric). Using such a design, it has been found that coloration can be adjusted in order to achieve certain desirable optical characteristics.

Claims (26)

1. An insulating glass (IG) window unit comprising:

first and second glass substrates spaced apart from one another so that a space is provided therebetween, at least the first glass substrate being thermally tempered and supporting a coating, wherein the coating consists essentially of:

a first dielectric layer comprising silicon nitride,

a lower contact layer comprising zinc oxide over and contacting the first dielectric layer comprising silicon nitride,

a layer comprising Ag over and contacting the lower contact layer comprising zinc oxide,

an upper contact layer comprising Ni and/or Cr, wherein the layer comprising Ag is located between and directly contacts each of said upper and lower contact layers, and

a second dielectric layer comprising silicon nitride located over and contacting the upper contact layer comprising Ni and/or Cr,

wherein the coating includes only one layer based on Ag, and wherein the IG window unit has a SHGC of no greater 0.55, a visible transmission of at least about 68%, transmissive a* color of from −5.5 to 0.0, transmissive b* color of from +0.5 to +3.5, glass side reflective a* color of from −4.0 to +2.0, and glass side reflective b* color of from −4.0 to +3.0.

2. The IG window unit of claim 1 , wherein the first dielectric layer comprising silicon nitride is characterized by Si x N y and is Si-rich so that x/y is from 0.76 to 2.0.

3. The IG window unit of claim 1 , wherein the first dielectric layer comprising silicon nitride has an index of refraction “n” of from 2.15 to 2.6 and an extinction coefficient “k” less than or equal to 0.07.

4. The IG window unit of claim 1 , wherein the first dielectric layer comprising g silicon nitride has an index of refraction “n” of from 2.2 to 2.5 and an extinction coefficient “k” less than or equal to 0.06.

5. The IG window unit of claim 1 , wherein the IG unit has a T UV of no greater than 0.29, and a sheet resistance of no greater than 8 ohms/square.

6. The IG window unit of claim 1 , wherein the IG unit has a T UV of no greater than 0.27, and a sheet resistance of no greater than 6 ohms/square.

7. The IG window unit of claim 1 , wherein the upper contact layer comprises NiCr.

8. The IG window unit of claim 1 , wherein the IG window unit has a SHGC of no greater 0.52, and a visible transmission of from about 68-72%.

9. The IG window unit of claim 1 , wherein the first dielectric layer comprising silicon nitride is in direct contact with the first glass substrate.

10. The IG window unit of claim 1 , wherein the first dielectric layer comprising silicon nitride is from 250 to 600 Å thick, and the lower contact layer comprising zinc oxide is from 50 to 200 Å thick.

11. The IG window unit of claim 1 , wherein the IG unit has transmissive a* color of from −5 to −2, transmissive b* color of from +0.5 to +2.5, glass side reflective a* color of from −2.0 to −0.5, and glass side reflective b* color of from −3.0 to −0.5.

12. The IG window unit of claim 1 , wherein the lower contact layer comprising zinc oxide is doped with aluminum, and is from about 50-200 Å thick, and wherein the layer comprising silver is from about 120-175 Å thick.

13. An insulating glass (IG) window unit comprising: first and second glass substrates spaced apart from one another so that a space is provided therebetween, at least the first glass substrate supporting a coating and being thermally tempered, wherein the coating consists essentially of:

a first dielectric layer comprising silicon nitride,

a lower contact layer comprising zinc oxide over and contacting the first dielectric layer comprising silicon nitride,

a layer comprising Ag over and contacting the lower contact layer,

an upper contact layer comprising Ni and/or Cr, wherein the layer comprising Ag is located between and directly contacts each of said upper and lower contact layers, and

a second dielectric layer comprising silicon nitride over and contacting the upper contact layer comprising Ni and/or Cr,

wherein the coating includes only one layer based on Ag, and wherein the IG window unit after heat treatment has a SHGC of no greater 0.55, glass side reflective a* color of from −3.0 to +1.0, glass side reflective b* color of from −3.0 to +1.5.

Assignments (5)
MERGER Recorded May 30, 2018
From: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.À R.L.
To: GUARDIAN EUROPE S.À R.L.
Reel/Frame 046834/0495 →
CORRECTIVE ASSIGNMENT TO CORRECT THE NAME AND ADDRESS OF THE ASSIGNEE PREVIOUSLY RECORDED ON REEL 044900 FRAME 0321. ASSIGNOR(S) HEREBY CONFIRMS THE CHANGE OF NAME. Recorded Feb 28, 2018
From: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.A.
To: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.À R.L.
Reel/Frame 045870/0001 →
CHANGE OF NAME Recorded Dec 18, 2017
From: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.A.
To: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.À.R.L.
Reel/Frame 044900/0321 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 29, 2017
From: GUARDIAN INDUSTRIES CORP.
To: GUARDIAN GLASS, LLC.
Reel/Frame 044053/0318 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 22, 2005
From: NUNEZ-REGUEIRO, JOSE; CORSNER, BRYCE; BASSETT, NANCY; DIETRICH, ANTON
To: GUARDIAN INDUSTRIES CORP.; CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.A.(C.R.V.C.)
Reel/Frame 017023/0031 →