Fluoropolymer-based masterbatch and its use for the extrusion of polyolefins
View Patent ↗The present invention relates to a masterbatch comprising by weight: from 1 to 50% of a blend of at least one fluoropolymer (A) and at least one interfacial agent (B); from 99 to 50% of a polyolefin (C); such that the two constituents (A) and (B) are intimately blended beforehand at a temperature such that at least one is in the melt state throughout its mass or on its surface, and are then blended with the polyolefin (C). The invention also relates to the use of the masterbatch as a processing aid for extruding a polyolefin (D), in particular for extruding a film-form polyolefin. The invention also relates to the process for obtaining the masterbatch.
1. A masterbatch comprising an intimate fluoropolymer/interfacial agent blend dispersed in a polyolefin matrix, comprising by weight:
from 1 to 50% of an intimate blend of at least one fluoropolymer (A) and at least one interfacial agent (B); and
from 99 to 50% of a polyolefin (C);
wherein the respective proportions of (A) and (B) by weight are such that (A)/(B) is between 30/70 and 70/30.
2. The masterbatch according to claim 1 , wherein the fluoropolymer is a polyvinylidene fluoride (PVDF) homopolymer or copolymer.
3. The masterbatch according to claim 2 , in which the PVDF contains, by weight, at least 50% vinylidene difluoride (VDF).
4. The masterbatch according to claim 3 , in which the PVDF contains, by weight, at least 75% VDF.
5. The masterbatch according to claim 4 , in which the PVDF contains, by weight, at least 85% VDF.
6. The masterbatch according to claim 2 , in which the comonomer is hexafluoropropylene (HFP).
7. The masterbatch according to claim 1 , wherein the interfacial agent (B) is polyoxyethylene glycol.
8. The masterbatch according to claim 1 , in which the proportion of (A) and (B) is from 1 to 30% per 99 to 70% of (C) respectively.
9. The masterbatch according to claim 8 , in which the proportion of (A) and (B) is from 1 to 10% per 99 to 90% of (C) respectively.
10. The masterbatch according to claim 1 , in which the respective proportions of (A) and (B) by weight are such that (A)/(B) is between 40/60 and 60/40.
11. A composition for the extrusion of polyolefin (D) comprising the masterbatch of claim 1 and a polyolefin (D).
12. The composition of claim 11 comprising an extruded film.
13. The composition of claim 11 wherein the proportion of masterbatch in the polyolefin (D) to be extruded is such that the quantity of (A)+(B) with respect to (D) is from 100 ppm to 3000 ppm.
14. The masterbatch of claim 1 , wherein the two constituents (A) and (B) are intimately blended beforehand at a temperature such that at least one is in the melt state throughout its mass or on its surface, and are then blended with the polyolefin (C).
15. The masterbatch according to claim 14 , wherein the blend of(A) and (B) is produced at between 10 and 120° C.
16. The masterbatch according to claim 14 , wherein the blend is produced at a temperature selected such that the interfacial agent (B) is in the melt state throughout its mass or on its surface and the fluoropolymer (A) is in the solid state.