Method of manufacturing a microelectronic component utilizing a tool comprising an ESD dissipative ceramic
View Patent ↗This invention relates to a dense ceramics having ESD dissipative characteristics, tunable volume and surface resistivities in semi-insulative range (10 3 -10 11 Ohm-cm), substantially pore free, high flexural strength, light colors, for desired ESD dissipation characteristics, structural reliability, high vision recognition, low wear and particulate contamination to be used as ESD dissipating tools, fixtures, load bearing elements, work surfaces, containers in manufacturing and assembling electrostatically sensitive microelectronic, electromagnetic, electro-optic components, devices and systems.
1. A method of manufacturing a microelectronic component comprising:
providing a tool including an ESD dissipative component, the ESD dissipative component being formed from a sintered composition including:
a base material comprising tetragonal zirconia; and
5 vol % to 60 vol % of a resistivity modifier, wherein
the ESD dissipative component has a volume resistivity ranging from 10 3 to 10 11 Ohm-cm, has an L* not less than 50 based using CIE 1976 L*a*b* scale on an LKE colorimeter, and a density not less than 95% of theoretical density; and
processing the microelectronic component utilizing the tool.
2. The method of claim 1 , wherein processing the microelectronic component is selected from the group consisting of lapping the microelectronic component, polishing the microelectronic component, cleaning the microelectronic component, handling the microelectronic component, wire bonding the microelectronic component, trimming the microelectronic component, cuffing the microelectronic component, dispensing adhesive onto the microelectronic component, and dispensing solder onto the microelectronic component.
3. The method of claim 1 , wherein the resistivity modifier comprises at least one of SnO 2 and ZnO.
4. The method of claim 1 , wherein the ESD dissipative component has a flexural strength not less than 500 MPa.
5. The method of claim 4 , wherein the ESD dissipative component has a flexural strength not less than 600 MPa.
6. The method of claim 5 , wherein the ESD dissipative component has a flexural strength not less than 700 MPa.
7. The method of claim 1 , wherein the tetragonal zirconia comprises about 2.5 to 4.5 mol % of a stabilizer.
8. The method of claim 7 , wherein the stabilizer comprises yttria.
9. The method of claim 1 , wherein the ESD dissipative component has less than 600 particles/cm 2 in a particle generation test.
10. The method of claim 1 , wherein the ESD dissipative component has a voltage decay time of less than 500 ms.
11. The method of claim 1 , wherein the ESD dissipative component is selected from the group consisting of MR (magnetoresistive) components for magnetic head manufacturing, HGA (head gimbal assembly) components, HSA (head stack assembly) components, HDD (hard disk drive) components, wafers handling components, wire bonding components, IC chip components, adhesive and solder nozzle components, wafer handling fixtures, end effector components, vacuum chuck components, electro-optic coating process components, and reticle components.
12. The method of claim 1 , wherein the sintered composition comprises 10 vol % to 50 vol % resistivity modifier.
13. The method of claim 12 , wherein the sintered composition comprises 20 vol % to 40 vol % resistivity modifier.
14. The method of claim 1 , wherein the ESD dissipative component has a density not less than 98% of theoretical density.
15. The method of claim 14 , wherein the ESD dissipative component has a density not less than 99% of theoretical density.
16. The method of claim 15 , wherein the ESD dissipative component has a density not less than 99.5% of theoretical density.
17. The method of claim 1 , wherein the volume resistivity of the ESD dissipative component is within a range of about 10 5 to 10 9 Ohm-cm.
18. The method of claim 17 , wherein the volume resistivity of the ESD dissipative component is within a range of about 10 6 to 10 9 Ohm-cm.
19. The method of claim 1 , wherein L* not less than 69.