Insulation compositions containing metallocene polymers
View Patent ↗Novel additive systems for metallocene based filled cable insulation are disclosed. These systems provide excellent protection against thermal degradation, better cure state and reduced dissipation factor after prolonged heat exposure. The additives may contain one or more hindered amine light stabilizers and amine antioxidants.
1. An insulation composition for electric cable consisting of:
(a) a metallocene ethylene-butene polymer;
(b) a filler; and
(c) an additive blend of:
(i) an amine antioxidant selected from the group consisting of 1,2-dihydro-2,2,4-trimethylquinoline, octylated diphenylamine, diphenyl-p-phenylene-diamine, 4,4′-di-(1,1-dimethylbenzyl)-diphenylamine, ethoxy-1,2-dihydro-2,2,4-trimethylquinoline, p,p′-dioctyldiphenylamine, N-(1,3-dimethylbutyl)-N′-phenyl-p-phenylene diamine, N-phenyl-N′-isopropyl-p-phenylene diamine, and p-phenylene diamine, and
(ii) a hindered amine light stabilizer.
2. An insulation composition according to claim 1 wherein said additive is from about 0.25% to about 2.5% by weight of said composition.
3. An insulation composition according to claim 1 wherein said additive is from about 0.5% to about 1.5% by weight of said composition.
4. An electrical cable comprising a conducting core; and an insulation covering said core, wherein the insulation consists of
(a) a metallocene ethylene-butene polymer;
(b) a filler; and
(c) an additive blend of:
(i) an amine antioxidant selected from the group consisting of 1,2-dihydro-2,2,4-trimethylquinoline, octylated diphenylamine, diphenyl-p-phenylene-diamine, 4,4′-di-(1,1-dimethylbenzyl)-diphenylamine, ethoxy-1,2-dihydro-2,2,4-trimethylquinoline, p,p′-dioctyldiphenylamine, N-(1,3-dimethylbutyl)-N′-phenyl-p-phenylene diamine, N-phenyl-N′-isopropyl-p-phenylene diamine, and p-phenylene diamine, and
(ii) a hindered amine light stabilizer.
5. An electrical cable according to claim 4 wherein said additive is from about 0.25% to about 2.5% by weight of said composition.
6. An electrical cable according to claim 4 wherein said additive is from about 0.5% to about 1.5% by weight of said composition.
7. An electrical cable according to claim 4 wherein said conducting core comprises copper or aluminum.