Polyimide matrix electrolyte
View Patent ↗A polymer matrix electrolyte (PME) includes a polyimide, at least one salt and at least one solvent intermixed. The PME is generally homogeneous as evidenced by its high level of optically clarity. The PME is stable through harsh temperature and pressure conditions. A method of forming a PME includes the steps of dissolving a polyimide in at least one solvent, adding at least one salt to the polyimide and the solvent, wherein said polyimide, salt and solvent become intermixed to form the PME, the PME being substantially optically clear.
1. A polymer matrix electrolyte (PME), comprising:
a polyimide, at least one lithium salt in a concentration of at least 0.5 moles of lithium per mole of imide ring provided by said polyimide, and at least one solvent all intermixed, wherein said polyimide is soluble at 25° C. in said solvent and said PME is substantially optically clear.
2. The PME of claim 1 , wherein said PME provides an optical clarity of at least 95% through a 1 mil film of said PME at 540 nm.
3. The PME of claim 1 , wherein said electrolyte provides an optical clarity of at least 99% through a 1 mil film of said PME at 540 nm.
4. The PME of claim 1 , wherein said lithium salt is selected from the group consisting of LiCl, LiBr, LiI, LiBOB, LiClO 4 , LiBF 4 , LiAsF 6 , LiPF 6 , LiCF 3 SO 3 , LiN(CF 3 SO 2 ) 2 and lithium bis(trifluorosulfonyl)imide (LiTFSi).
5. The PME of claim 1 , wherein a repeat unit weight per imide ring of said polyimide is no more than 350.
6. The PME of claim 1 , wherein a repeat unit weight per imide ring of said polyimide is no more than 300.
7. The PME of claim 1 , wherein a repeat unit weight per imide ring of said polyimide is no more than 250.
8. The PME of claim 1 , wherein said polyimide is soluble at 25° C. in at least one solvent selected from the group consisting of N-methylpyrrolidinone (NMP), dimethylacetamide (DMAc) and dimethylformamide (DMF).
9. The PME of claim 1 , wherein an ionic conductivity of said PME at 25° C. is at least 1×10 −4 S/cm.
10. The PME of claim 1 , wherein an ionic conductivity of said PME at 25° C. is at least 3×10 −4 S/cm.
11. The PME of claim 1 , wherein a concentration of said lithium salt is between 0.5 to 2.0 moles Li per mole of imide ring provided by said polyimide.
12. The PME of claim 1 , wherein a concentration of said lithium salt is between 1.2 to 2.0 moles Li per mole of imide ring provided by said polyimide.
13. The PME of claim 1 , wherein said salt and said polyimide do not provide any absorption peaks between 1630 and 1690 cm −1 , said PME providing at least one absorption between about 1630 and 1690 cm −1 .
14. A method of forming a polymer matrix electrolyte (PME), comprising the steps of:
dissolving a polyimide in at least one solvent,
adding at least one lithium salt in a concentration of at least 0.5 moles of lithium per mole of imide ring provided by said polyimide to said polyimide and said solvent, wherein said polyimide, said salt and said solvent become intermixed, wherein said polyimide is soluble at 25° C. in said solvent and said PME is substantially optically clear.