IP Library Granted Patent US 7,547,106
Granted Patent B2
US 7,547,106 · App. 11/192,529 · Granted Jun 16, 2009

Simulated high refractive index glass

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Quick Facts
Patent No.
US 7,547,106
App. No.
11/192,529
Granted
Jun 16, 2009
Kind
B2
Abstract

A method for modifying the appearance of a substrate is disclosed. The method includes providing a substrate having first and second opposing surfaces and depositing a reflectance modifying coating on at least a portion of the first surface of the substrate, wherein the second surface has a visible light reflectance (R 1 ) ranging from 5 to 20 percent.

Claims (19)

1. A method for modifying the appearance of a substrate comprising:

providing a substrate having first and second opposing surfaces; and

depositing a reflectance modifying coating on at least a portion of the first surface of the substrate, wherein the second surface has a visible light reflectance (R1) ranging from 5 to 20 percent, wherein the reflectance modifying coating provides the coated article with a ΔE reflectance of less than or equal to 25 and a ΔE transmittance of less than or equal to 8.

2. The method according to claim 1 , wherein the visible light reflectance from the second surface ranges from 9 to 15 percent.

3. The method according to claim 1 , wherein the reflectance modifying coating has a Δn of less than or equal to 0.35 at a wavelength ranging from 370 nm to 700 nm.

4. The method according to claim 1 , wherein the reflectance modifying coating has a refractive index ranging from 1.7 to 2.2 at 550 nm.

5. The method according to claim 1 , wherein the reflectance modifying coating is selected from Al 2 O 3 , SnO 2 , Ta 2 O 5 , TiO 2 , ZrO 2 , ZnO and Zn x Sn 1−x O 2−x where x is greater than 0 but less than 1, and mixtures thereof.

6. The method according to claim 1 , wherein the step of depositing is accomplished via a CVD process.

7. The method according to claim 1 , wherein the reflectance modifying coating has a thickness equal to or less than 200 Å.

8. The method according to claim 7 , wherein the reflectance modifying coating has a thickness ranging from 50 Å to 175 Å.

9. The method according to claim 1 , wherein the substrate is glass.

10. The method according to claim 9 , wherein the substrate is a glass float ribbon.

11. A method for modifying the appearance of a substrate comprising:

providing a substrate having first and second opposing surfaces; and

depositing a reflectance modifying coating by a CVD process on at least a portion of the first surface of a substrate, wherein the second surface has a visible light reflectance (R 1 ) ranging from 5 to 20 percent, wherein the reflectance modifying coating provides the coated article with a ΔE reflectance of less than or equal to 25 and a ΔE transmittance of less than or equal to 8.

12. The method according to claim 11 , wherein the reflectance modifying coating is selected from Al 2 O 3 , SnO 2 , Ta 2 O 5 , TiO 2 , ZrO 2 , ZnO and Zn x Sn 1−x O 2−x where x is greater than 0 but less than 1 and mixtures thereof.

13. A method for providing a brilliant appearance to an automotive vision panel, the method comprising:

providing an automotive vision panel having a first surface and a second surface; and

depositing a reflectance modifying coating on at least a portion of the first surface of the vision panel, wherein the reflectance modifying coating comprises at least one material having a refractive index in the range of 1.7 to 2.2 at a wavelength of 550 nm, wherein the reflectance modifying coating has a thickness of less than or equal to 200 Å, wherein the reflectance modifying coating provides a Δn of less than or equal to 0.30 over a range of 370 nm to 700 nm, wherein the reflectance modifying coating provides a ΔE reflectance of less than or equal to 25 and a ΔE transmittance of less than or equal to 8, and wherein the reflectance modifying coating provides the second surface with a visible light reflectance in the range of 5 to 20 percent.

Assignments (6)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 8, 2021
From: VITRO, S.A.B. DE C.V.
To: VITRO FLAT GLASS LLC
Reel/Frame 058052/0526 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 11, 2019
From: VITRO, S.A.B. DE C.V.
To: VITRO FLAT GLASS LLC
Reel/Frame 048048/0177 →
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEE ADDRESS PREVIOUSLY RECORDED AT REEL: 040473 FRAME: 0455. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded May 3, 2017
From: PPG INDUSTRIES OHIO, INC.
To: VITRO, S.A.B. DE C.V.
Reel/Frame 042393/0520 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 25, 2016
From: PPG INDUSTRIES OHIO, INC.
To: VITRO, S.A.B. DE C.V.
Reel/Frame 040473/0455 →
CORRECTIVE ASSIGNENT TO CORRECT THE NAME OF THE SECOND ASSIGNOR. PREVIOUSLY RECORDED ON REEL 017004 FRAME 0417. Recorded Feb 17, 2006
From: LIN, CHIA-CHENG; SHELESTAK, LARRY J.
To: PPG INDUSTRIESOHIO, INC.
Reel/Frame 017566/0184 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 19, 2005
From: LIN, CHIA-CHENG; SHESESTAK, LARRY J.
To: PPG INDUSTRIES OHIO, INC.
Reel/Frame 017004/0417 →