IP Library Granted Patent US 7,727,634
Granted Patent B2
US 7,727,634 · App. 11/193,885 · Granted Jun 1, 2010

Decorative glass laminate containing an ultraviolet printed image thereon and a method for preparing said decorative glass laminate

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Quick Facts
Patent No.
US 7,727,634
App. No.
11/193,885
Granted
Jun 1, 2010
Kind
B2
Abstract

This invention is directed to a plastic composite comprising color images printed onto a polymeric support film using UV ink. The polymeric support film layer may be bonded to a polymeric film selected from the group consisting of aliphatic polyurethane and ethyl vinyl acetate. The combined laminate can then optionally be disposed between two layers of plasticized PVB, forming the plastic composite. The plastic composite can then be placed between two sheets of glass forming the final laminated glass product. Preferably, when the UV image is printed on the polymeric support film, the image is only partially cured by a UV lamp. After the polymeric support film is contacted with the polymeric film, with the partially cured UV image therebetween, the laminate is exposed to a second UV lamp operating at full power so as to completely cure the UV image.

Claims (31)

1. An interlayer for laminated glass, the interlayer comprising

a polymeric support film supporting at least one color image printed with UV ink and a polymeric film bonded to the polymeric support film, such that the color image is directly deposited on said polymeric support film and between the polymeric support film and the polymeric film, wherein the polymeric film is a thermoplastic sheet comprising a layer or coating of either polyurethane or ethyl vinyl acetate and wherein said polymeric support film is plasticized polyvinyl butyral.

2. The interlayer of claim 1 , wherein the polymeric film is ethyl vinyl acetate.

3. The interlayer of claim 2 , wherein the polymeric film is applied as a sheet.

4. The interlayer of claim 2 , wherein the polymeric film is applied as a topical adhesion promoter.

5. The interlayer of claim 1 , wherein the thermoplastic sheet is selected from the group consisting of polyvinyl butyral and polyethylene terephthalate.

6. The interlayer of claim 1 , wherein the color image is printed on the polymeric support film using inkjet printing technology.

7. The interlayer of claim 1 , wherein said interlayer is bonded between two adhesive layers.

8. The interlayer of claim 7 , wherein the adhesive layers are individually selected from the group consisting of polyurethane, ethylene vinyl acetate copolymer, plasticized polyvinyl chloride and plasticized polyvinyl butyral.

9. The interlayer of claim 7 , wherein the adhesive layers are plasticized polyvinyl butyral.

10. The interlayer of claim 1 , further comprising an adhesive layer bonded to the polymeric film.

11. The interlayer of claim 10 , wherein the adhesive layer is selected from the group consisting of polyurethane, ethylene vinyl acetate copolymer, plasticized polyvinyl chloride and plasticized polyvinyl butyral.

12. The interlayer of claim 10 , wherein the adhesive layer is plasticized polyvinyl butyral.

13. The interlayer of claim 1 , wherein the thickness of the polymeric film is less than or equal to one half the thickness of the polymeric support film.

14. The interlayer of claim 1 , wherein the color image is selected from the group consisting of a logo, symbol, geometric pattern, photograph, alphanumeric characters and combinations thereof.

15. The laminated glass composite of claim 1 , wherein said UV ink has an acrylic content.

16. A laminated glass composite comprising an image layer disposed between two glass sheets, the image layer comprising a polymeric support film supporting at least one color image printed with UV ink and a polymeric film bonded to the polymeric support film, such that the color image is directly deposited on said polymeric support film and between the polymeric support film and the polymeric film, wherein the polymeric film is a thermoplastic sheet comprising a layer or coating of either polyurethane or ethyl vinyl acetate and wherein said polymeric support film is plasticized polyvinyl butyral.

17. The laminated glass composite of claim 16 , wherein the polymeric film is ethyl vinyl acetate.

18. The laminated glass composite of claim 16 , wherein the polymeric film is applied as a sheet.

19. The laminated glass composite of claim 16 , wherein the polymeric film is applied as a topical adhesion promoter.

20. The laminated glass composite of claim 16 , wherein the thermoplastic sheet is selected from the group consisting of polyvinyl butyral and polyethylene terephthalate.

21. The laminated glass composite of claim 16 , wherein the color image is printed on the polymeric support film using inkjet printing technology.

22. The laminated glass composite of claim 16 , further comprising the image layer being bonded between two adhesive layers.

23. The laminated glass composite of claim 22 , wherein the adhesive layers are individually selected from the group consisting of polyurethane, ethylene vinyl acetate copolymer, plasticized polyvinyl chloride and plasticized polyvinyl butyral.

24. The laminated glass composite of claim 22 , wherein the adhesive layers are plasticized polyvinyl butyral.

25. The laminated glass composite of claim 16 , further comprising an adhesive layer bonded to the polymeric film.

26. The laminated glass composite of claim 25 , wherein the adhesive layer is selected from the group consisting of polyurethane, ethylene vinyl acetate copolymer, plasticized polyvinyl chloride and plasticized polyvinyl butyral.

27. The laminated glass composite of claim 25 , wherein the adhesive layer is plasticized polyvinyl butyral.

28. The laminated glass composite of claim 16 , wherein the thickness of the polymeric film is less than or equal to one half the thickness of the polymeric support film.

29. The laminated glass composite of claim 16 , wherein the color image is selected from the group consisting of a logo, symbol, geometric pattern, photograph, alphanumeric characters and combinations thereof.

30. The laminated glass composite of claim 16 , wherein said UV ink has an acrylic content.

Assignments (7)
RELEASE OF SECURITY INTEREST Recorded Jul 17, 2012
From: DEUTSCHE BANK TRUST COMPANY AMERICAS, AS COLLATERAL AGENT
To: SOLUTIA INC.; CPFILMS INC.; FLEXSYS AMERICA L.P.
Reel/Frame 028563/0241 →
SECURITY AGREEMENT Recorded May 17, 2010
From: SOLUTIA INC.; CP FILMS INC.; FLEXSYS AMERICA L.P.
To: DEUTSCHE BANK TRUST COMPANY AMERICAS, AS COLLATERAL AGENT
Reel/Frame 024390/0281 →
RELEASE OF TERM LOAN SECURITY INTEREST IN PATENTS - REEL/FRAME 022610/0697 Recorded Mar 30, 2010
From: CITIBANK, N.A.
To: SOLUTIA INC.; CPFILMS INC.; FLEXSYS AMERICA L.P.
Reel/Frame 024151/0513 →
RELEASE OF ABL SECURITY INTEREST IN PATENTS - REEL/FRAME 022610/0495 Recorded Mar 30, 2010
From: CITIBANK, N.A.
To: SOLUTIA INC.; CPFILMS INC.; FLEXSYS AMERICA L.P.
Reel/Frame 024151/0469 →
ABL PATENT SECURITY AGREEMENT Recorded Apr 29, 2009
From: SOLUTIA INC.; CPFILMS INC.; FLEXSYS AMERICA L.P.
To: CITIBANK, N.A.
Reel/Frame 022610/0495 →
TERM LOAN PATENT SECURITY AGREEMENT Recorded Apr 29, 2009
From: SOLUTIA INC.; CPFILMS INC.; FLEXSYS AMERICA L.P.
To: CITIBANK, N.A.
Reel/Frame 022610/0697 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 22, 2005
From: YACOVONE, VINCENT J.
To: SOLUTIA INC.
Reel/Frame 017142/0692 →