IP Library Granted Patent US 7,495,383
Granted Patent B2
US 7,495,383 · App. 11/195,199 · Granted Feb 24, 2009

Phosphor based on a combination of quantum dot and conventional phosphors

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Quick Facts
Patent No.
US 7,495,383
App. No.
11/195,199
Granted
Feb 24, 2009
Kind
B2
Abstract

A phosphor composition and a light source constructed therefrom are disclosed. The phosphor composition includes first and second phosphors. The first phosphor includes first phosphor particles that convert light of an excitation wavelength to light having a first spectrum characterized by an intensity of light that varies as a function of wavelength. The first phosphor particles are chosen such that the first spectrum is independent of the size of the particles. The second phosphor includes particles of a QD phosphor that convert the excitation light to light in a QD phosphor spectrum. The first phosphor particles and the QD phosphor particles are present in a ratio of concentrations. The ratio, the first phosphor particles, and the QD phosphor particles are chosen such that a combined spectrum has an intensity that is more uniform as a function of wavelength than either the QD phosphor spectrum or the first spectrum.

Claims (29)

1. A phosphor composition comprising:

first phosphor particles of a first size, said first phosphor particles of a first size converting light of an excitation wavelength to light having a first spectrum characterized by an intensity of light that varies as a function of wavelength, said first spectrum being independent of said size of said first phosphor particles; and

particles of a QD phosphor of a second size that convert light of said excitation wavelength to light having a QD phosphor spectrum characterized by an intensity of light that varies as a function of wavelength;

wherein each of said first phosphor particles of a first size are coated with one or more of said particles of a QD phosphor of a second size.

2. The phosphor composition of claim 1 wherein said first phosphor particles of a first size comprise particles of a first chemical composition and said particles of a QD phosphor of a second size comprise phosphors of a second chemical composition.

3. The phosphor composition of claim 2 wherein said first chemical composition is different from said second chemical composition.

4. The phosphor composition of claim 1 wherein said first phosphor particles of a first size and said particles of a QD phosphor of a second size are present in a ratio of concentrations and wherein said ratio, said first phosphor particles of a first size, and said particles of a QD phosphor of a second size are chosen such that a combined spectrum comprising said QD phosphor spectrum and said first spectrum has an intensity that is more uniform as a function of wavelength than either said QD phosphor spectrum or said first spectrum.

5. The phosphor composition of claim 4 wherein said combined spectrum is perceived to be white light.

6. The phosphor composition of claim 1 wherein said first phosphor particles of a first size comprise particles chosen from the group consisting of garnet, sulphide, thiometallate, silicate, oxides, oxynitrides, nitrides, and selenide based phosphor.

7. The phosphor composition of claim 6 wherein said first phosphor particles of a first size are doped with a rare earth element.

8. The phosphor composition of claim 1 wherein said particles of a QD phosphor of a second size comprise CdS, CdSe, CdTe, CdPo, ZnS, ZnSe, ZnTe, ZnPo, Mgs, MgSe, MgTe, PbSe, PbS, PbTe, HgS, HgSe, HgTe, Cd(S 1-x ,Se x ), BaTiO 3 , PbZrO 3 , PbZr z Ti 1-z O 3 , SrTiO 3 , SrTiO 3 , LaMnO 3 , CaMnO 3 , and La 1-x Ca x MnO 3 .

9. The phosphor composition of claim 1 wherein said first phosphor particles of a first size are coated with a layer of material that provides protection from moisture.

10. The phosphor composition of claim 1 wherein said particles of a QD phosphor of a second size are coated with a layer of material that inhibits said particles of a QD phosphor of a second size from sticking to one another.

11. A light source comprising:

an excitation light source that emits excitation light of an excitation wavelength;

a layer of phosphor comprising:

first phosphor particles of a first size, said first phosphor particles of a first size converting light of an excitation wavelength to light having a first spectrum characterized by an intensity of light that varies as a function of wavelength, said first spectrum being independent of said size of said first phosphor particles; and

particles of a QD phosphor of a second size that convert light of said excitation wavelength to light having a QD phosphor spectrum characterized by an intensity of light that varies as a function of wavelength;

wherein each of said first phosphor particles of a first size are coated with one or more of said particles of a QD phosphor of a second size.

12. The light source of claim 11 wherein said first phosphor particles of a first size comprise particles of a first chemical composition and said particles of a QD phosphor of a second size comprise phosphors of a second chemical composition.

13. The light source of claim 12 wherein said first chemical composition is different from said second chemical composition.

14. The light source of claim 11 wherein said first phosphor particles of a first size and said particles of a QD phosphor of a second size are present in a ratio of concentrations and wherein said ratio, said first phosphor particles of a first size, and said particles of a QD phosphor of a second size are chosen such that a combined spectrum comprising said QD phosphor spectrum and said first spectrum has an intensity that is more uniform as a function of wavelength than either said QD phosphor spectrum or said first spectrum.

15. The light source of claim 14 wherein said combined spectrum is perceived to be white light.

16. The light source of claim 15 wherein said combined spectrum further comprises a portion of said excitation light.

17. The light source of claim 11 wherein said first phosphor particles of a first size comprise particles chosen from the group consisting of garnet, sulphide, thiometallate, silicate, oxides, oxynitrides, nitrides, and selenide based phosphor.

18. The light source of claim 17 wherein said first phosphor particles of a first size are doped with a rare earth element.

19. The light source of claim 11 wherein said particles of a QD phosphor of a second size comprise CdS, CdSe, CdTe, CdPo, ZnS, ZnSe, ZnTe, ZnPo, Mgs, MgSe, MgTe, PbSe, PbS, PbTe, HgS, HgSe, HgTe, Cd(S 1-x ,Se x ), BaTiO 3 , PbZrO 3 , PbZr z Ti 1-z O 3 , Ba x Sr 1-x TiO 3 , LaMnO 3 , CaMnO 3 , and La 1-x Ca x MnO 3 .

20. The light source of claim 11 wherein said first phosphor particles of a first size are coated with a layer of material that provides protection from moisture.

21. The light source of claim 11 wherein said particles of a QD phosphor of a second size are coated with a layer of material that inhibits said particles of a QD phosphor of a second size from sticking to one another.

Assignments (6)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 17, 2016
From: INTELLECTUAL DISCOVERY CO. LTD.
To: DOCUMENT SECURITY SYSTEMS, INC.
Reel/Frame 040744/0174 →
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEE NAME PREVIOUSLY RECORDED AT REEL: 017206 FRAME: 0666. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded May 6, 2016
From: AGILENT TECHNOLOGIES, INC.
To: AVAGO TECHNOLOGIES GENERAL IP (SINGAPORE) PTE. LTD.
Reel/Frame 038632/0662 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 17, 2012
From: AVAGO TECHNOLOGIES GENERAL IP (SINGAPORE) PTE. LTD.; AVAGO TECHNOLOGIES ECBU IP (SINGAPORE) PTE. LTD.; AVAGO TECHNOLOGIES FIBER IP (SINGAPORE) PTE. LTD.
To: INTELLECTUAL DISCOVERY CO., LTD.
Reel/Frame 028972/0733 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 25, 2006
From: AVAGO TECHNOLOGIES GENERAL IP (SINGAPORE) PTE. LTD.
To: AVAGO TECHNOLOGIES ECBU IP (SINGAPORE) PTE. LTD.
Reel/Frame 017675/0626 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 22, 2006
From: AGILENT TECHNOLOGIES, INC.
To: AVAGO TECHNOLOGIES GENERAL IP PTE. LTD.
Reel/Frame 017206/0666 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 30, 2005
From: CHUA, JANET BEE YIN; LAU, YUE HOONG
To: AGILENT TECHNOLOGIES INC.
Reel/Frame 016473/0181 →